Synthesis of stable carboxylate phosphabetaines - Potential ligands of the metal complexes

A practical route is described for the preparation of α‐imido‐β‐diarylphosphorylpropanoates based on the phosphine‐catalyzed α‐umpolung/β‐Michael addition reaction. One of the products has been tested for coordination the Gd3+ cation using NMR relaxation method in solution and by IR spectroscopy to solids. The exact structures of two isomers of the obtained complex have been determined by single crystal analysis. The structures of all isomers were investigated by quantum‐chemical calculations in solution. Quantum‐chemical calculations results show the presence of stereoselective effect in solution: the trans‐isomer with two ligands having different chirality is energetically more favorable. The cis‐isomer with ligands of different chirality is the least advantageous in terms of energy and therefore presents in solution in small amounts. The cis‐ and trans‐isomers with two ligands of the same chirality are very close in energy but are somewhat inferior to the most stable isomer.

show abstract

New α‐Imido‐β‐diarylphosphorylpropanoates and their Complexes with Gadolinium(III)

Il'in

Serov

Khannanov

et al. 2022

ChemistrySelect

View full text Add to dashboard Cite

show abstract

New biologically active phosphonium salts based on 3-(diphenylphosphino)propionic acid and unsaturated amides

et al. 2020

View full text Add to dashboard Cite

Tris(3-fluorophenyl)phosphine in reactions with acrylic acid and its derivatives: crystal structure and biological activity of the reaction products

Romanov,

Nafikova,

Shulaeva

et al. 2024

Russ Chem Bull

View full text Add to dashboard Cite

scite is a Brooklyn-based organization that helps researchers better discover and understand research articles through Smart Citations–citations that display the context of the citation and describe whether the article provides supporting or contrasting evidence. scite is used by students and researchers from around the world and is funded in part by the National Science Foundation and the National Institute on Drug Abuse of the National Institutes of Health.

Contact Info

customersupport@researchsolutions.com

10624 S. Eastern Ave., Ste. A-614

Henderson, NV 89052, USA

This site is protected by reCAPTCHA and the Google Privacy Policy and Terms of Service apply.

Blog Terms and Conditions API Terms Privacy Policy Contact Cookie Preferences Do Not Sell or Share My Personal Information

Made with 💙 for researchers

Part of the Research Solutions Family.

Synthesis of stable carboxylate phosphabetaines - Potential ligands of the metal complexes

Cited by 11 publications

References 27 publications

New α‐Imido‐β‐diarylphosphorylpropanoates and their Complexes with Gadolinium(III)

New α‐Imido‐β‐diarylphosphorylpropanoates and their Complexes with Gadolinium(III)

New biologically active phosphonium salts based on 3-(diphenylphosphino)propionic acid and unsaturated amides

Tris(3-fluorophenyl)phosphine in reactions with acrylic acid and its derivatives: crystal structure and biological activity of the reaction products

Contact Info

Product

Resources

About