Synthesis of Stable Dimeric Phthalocyanine J-Type Complexes and Investigation of Their Nucleophilic Properties

Tolbin, Alexander Yu.; Sheinin, V. B.; Койфман, О. И.; Tomilova, Larisa G.

doi:10.6060/mhc150454t

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Cited by 6 publications

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“…Preparation of bis(2-hydroxy-9(10),16(17),23(24)-tri-tert-butylphthalocyanine) (2): Dimeric complex 1 [9] (120 mg, 0.08 mmol) was completely dissolved in concentrated sulfuric acid (25 mL), then the resulting dark brown solution was poured onto ice to precipitate target metal-free dimer 2 (93 mg, yield -80%). MALDI-TOF (matrix -2,5- …”

Section: Methodsmentioning

confidence: 99%

Unusual self-assembled nanoaggregation of the thermally stable metal-free slipped-cofacial J-type phthalocyanine dimer

Tolbin

Tomilova

2017

Chinese Chemical Letters

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Section: Methodsmentioning

confidence: 99%

Unusual self-assembled nanoaggregation of the thermally stable metal-free slipped-cofacial J-type phthalocyanine dimer

Tolbin

Tomilova

2017

Chinese Chemical Letters

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Glycoconjugated Phthalocyanines as Photosensitizers for PDT – Overcoming Aggregation in Solution

2019

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A series of new glycoconjugated zinc(II) phthalocyanines (Pcs) was synthesized and fully characterized. The major focus of the structural design for these new Pcs was upon the reduction of aggregate formation in solution. Therefore, the aglycons of the Pc‐linked sugars, the number and the position of the carbohydrate substituents on the Pc and the linker between sugar and Pc were varied. Specifically, di‐ and octasubstituted zinc(II) phthalocyanines with triazole and C–C linkages were synthesized and their aggregation behaviour was investigated by UV/Vis‐, CD‐ and NMR spectroscopy. The C‐glycosidically decorated Pcs described here are the first compound types of this kind. These C‐glycosidically substituted Pcs were shown to not form any aggregation in solution and hence, are considered to be potential photosensitizers in photodynamic therapy. All Pcs synthesized in this study exhibited excellent photophysical properties for use as photosensitizers (λmax > 675 nm with εmax > 105 m–1 cm–1). Preliminary cytotoxicity studies of the Pcs presented here showed that all Pcs are photodynamically effective.

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High-performance optical limiters based on stable phthalocyanine J-type dimers

Tolbin

Savelyev

Gerasimenko

et al. 2016

Chemical Physics Letters

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Synthesis of Stable Dimeric Phthalocyanine J-Type Complexes and Investigation of Their Nucleophilic Properties

Abstract: Metallation of the low-symmetry 2-hydroxy-9(10),16(17), 23(24)-tri-tert-butylphthalocyanine (ligand)

Cited by 6 publications

References 17 publications

Unusual self-assembled nanoaggregation of the thermally stable metal-free slipped-cofacial J-type phthalocyanine dimer

Unusual self-assembled nanoaggregation of the thermally stable metal-free slipped-cofacial J-type phthalocyanine dimer

Glycoconjugated Phthalocyanines as Photosensitizers for PDT – Overcoming Aggregation in Solution

High-performance optical limiters based on stable phthalocyanine J-type dimers

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