Synthesis of stereoregular polymyrcenes using neodymium-, iron- and copper-based catalysts

Ricci, Giovanni; Boccia, Antonella Caterina; Palucci, Benedetta; Sommazzi, Anna; Masi, Francesco; Scoti, Miriam; De Stefano, Fabio; De Rosa, Claudio

doi:10.1039/d3py01309j

Polym. Chem.

2024

DOI: 10.1039/d3py01309j

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Synthesis of stereoregular polymyrcenes using neodymium-, iron- and copper-based catalysts

Giovanni Ricci,

Antonella Caterina Boccia,

Benedetta Palucci

et al.

Abstract: β-myrcene was polymerized with catalysts based on pyridyl-imino complexes of neodymium, iron and copper. Highly stereoregular polymers were obtained: in particular neodymium catalysts gave highly cis-1,4 polymers (≥97%), while iron...

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Cited by 3 publications

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Iminopyridine Manganese and Nickel Complexes: Synthesis, Characterization and Behavior in the Polymerization of 1,3-Butadiene

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Synthesis of stereoregular polymyrcenes using neodymium-, iron- and copper-based catalysts

Abstract: β-myrcene was polymerized with catalysts based on pyridyl-imino complexes of neodymium, iron and copper. Highly stereoregular polymers were obtained: in particular neodymium catalysts gave highly cis-1,4 polymers (≥97%), while iron...

Cited by 3 publications

References 25 publications

Iminopyridine Manganese and Nickel Complexes: Synthesis, Characterization and Behavior in the Polymerization of 1,3-Butadiene

Iminopyridine Manganese and Nickel Complexes: Synthesis, Characterization and Behavior in the Polymerization of 1,3-Butadiene

Cis-1,4-specific polymerization of 1,3-conjugated dienes with bis(benzimidazole)NiCl2 catalyst system

Polymerization of isoprene and butadiene with unparalleled stereoselectivity catalysed by rare-earth metal cationic species bearing a novel tridentate ligand

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