Synthesis of sulfur-containing polycarbonate block copolymers via Salen-metal catalyzed copolymerization of CO₂, propylene oxide, and phthalic thioanhydride

Synthesis and Characterization of Zn-Salophen Complexes with Different D–A Distances: An Approach to Tuning the Intersystem-Crossing Process

“…Metallosalen/salophen (bis(salicylidene)ethylenediamine and bis(salicylidene)phenyldiamine) complexes have attracted considerable attention due to their versatile applications in catalysis [1][2][3][4][5][6][7][8][9][10], supramolecular chemistry [11][12][13][14][15][16][17][18], optical materials [19][20][21], and biological sensors or therapeutics [22,23] because of their rich chemistry and ease of manipulation of organic ligands. Among these complexes, zinc (II) salen/salophen complexes are of particular interest due to the non-redox nature and d 10 closed-shell configuration of the Zn 2+ ion, making them suitable for ligand-dependent fluorescent materials [24].…”