1984
DOI: 10.1016/s0040-4020(01)91324-9
|View full text |Cite
|
Sign up to set email alerts
|

Synthesis of tetrahydroxy-1,4-benzoquinone biscarbonate and hexahydroxybenzene triscarbonate-new organic carbon oxides

Help me understand this report

Search citation statements

Order By: Relevance

Paper Sections

Select...
3
2

Citation Types

0
5
0

Year Published

1985
1985
2021
2021

Publication Types

Select...
6
1

Relationship

0
7

Authors

Journals

citations
Cited by 11 publications
(5 citation statements)
references
References 5 publications
0
5
0
Order By: Relevance
“…The structure, bonding and stability of chemically bound C n O n have been explored in a large number of publications (Frenking, 1990; Schröder et al, 1998, 1999; Talbi and Chandler, 2000; Sabzyan and Noorbala, 2003; Zhou et al, 2010; Bao et al, 2012; Guo et al, 2012; Hu et al, 2012; Dixon et al, 2015; Liu et al, 2015; Hansen et al, 2016). To our surprise, larger CO oligomers in poly-cyclic form with n = 8, 9, 10, 12 were reported early (in 1967 and 1984; Verter and Dominic, 1967; Nallaiah, 1984). Their easy accessibility is in accordance with their good thermodynamic stability with respect to nCO (Schröder et al, 1999), and these low-lying clusters surely cannot be used for HEDMs.…”
Section: Introductionmentioning
confidence: 69%
“…The structure, bonding and stability of chemically bound C n O n have been explored in a large number of publications (Frenking, 1990; Schröder et al, 1998, 1999; Talbi and Chandler, 2000; Sabzyan and Noorbala, 2003; Zhou et al, 2010; Bao et al, 2012; Guo et al, 2012; Hu et al, 2012; Dixon et al, 2015; Liu et al, 2015; Hansen et al, 2016). To our surprise, larger CO oligomers in poly-cyclic form with n = 8, 9, 10, 12 were reported early (in 1967 and 1984; Verter and Dominic, 1967; Nallaiah, 1984). Their easy accessibility is in accordance with their good thermodynamic stability with respect to nCO (Schröder et al, 1999), and these low-lying clusters surely cannot be used for HEDMs.…”
Section: Introductionmentioning
confidence: 69%
“…To date, several of the polycyclic neutral oxocarbons, such as 1 – 4 , have been synthesized by several research groups. [ 52–54 ] However, they are generally less stable. [ 52–54 ] Their reactivity may be associated with their small positive or negative TREs.…”
Section: Resultsmentioning
confidence: 99%
“…[ 52–54 ] However, they are generally less stable. [ 52–54 ] Their reactivity may be associated with their small positive or negative TREs. Compounds 5 – 18 are experimentally unknown.…”
Section: Resultsmentioning
confidence: 99%
“…In this paper, we present our theoretical investigations on the structure and stability of a set of novel neutral oligomeric polycyclic oxocarbons. Indeed, “organic carbon oxides” ( 1 − 4 , Scheme ) have been synthesized from tetrahydroxy-1,4-benzoquinone and hexahydroxybenzene with carbonyl chloride or oxalyl chloride by Nallaiah ( 1 , 2 ) and by Verter ( 3 , 4 ) . It is found that 1 and 2 are extremely sensitive to heat and moisture and darken and decompose on heating at 45−53 °C with brisk evolution of gas, and 3 as well as 4 decompose easily under reduced pressure upon removal of the solvent .…”
Section: Introductionmentioning
confidence: 99%
“…Indeed, “organic carbon oxides” ( 1 − 4 , Scheme ) have been synthesized from tetrahydroxy-1,4-benzoquinone and hexahydroxybenzene with carbonyl chloride or oxalyl chloride by Nallaiah ( 1 , 2 ) and by Verter ( 3 , 4 ) . It is found that 1 and 2 are extremely sensitive to heat and moisture and darken and decompose on heating at 45−53 °C with brisk evolution of gas, and 3 as well as 4 decompose easily under reduced pressure upon removal of the solvent . The structure of 1 was computed at the HF/6-31G* level by Kwon and Koo .…”
Section: Introductionmentioning
confidence: 99%