Synthesis of tetrasubstituted acylaminophthalocyanines of cobalt

Милаева, Е. Р.; Kolnin, S. D.; Petrosyan, V. S.

doi:10.1007/bf01457805

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“…According to Smirnov and co-workers [86], up to 76% yields of tetrachloro-(3) and tetranitro-(4) substituted Pcs can be observed, while yield of the corresponding tetrabromo derivative 5 is significantly lower [87] ( Table 1). It was suggested in two reports [88,89] that the reaction between sterically hindered PNs and rare-earth salts leads to the selective formation of the single-decker Pc complexes 6-9…”

Section: Template Synthesis From Phthalogensmentioning

confidence: 99%

“…The most simple, but the less selective method for the preparation of rare-earth heteroleptic The reaction between single-decker rare-earth Pc and the corresponding PN was used for the preparation of heteroleptic complexes 135-150 (Scheme 28, Table 5). In the case of heteroleptic double-decker Pcs 135-142, a large excess of the PN was applied as it was employed as a reactant and a solvent (Scheme 28, conditions 1) [86,87,89,98,273,274]. This synthetic approach can be used for the preparation of double-decker heteroleptic complexes with electron-acceptor (137)(138)(139) as well as bulky (140)(141)(142) substituents in quite good yields (28 -75%, Table 5) [86,87,89].…”

Section: Phthalocyanine-metal-phthalocyanine Complexesmentioning

confidence: 99%

“…In the case of heteroleptic double-decker Pcs 135-142, a large excess of the PN was applied as it was employed as a reactant and a solvent (Scheme 28, conditions 1) [86,87,89,98,273,274]. This synthetic approach can be used for the preparation of double-decker heteroleptic complexes with electron-acceptor (137)(138)(139) as well as bulky (140)(141)(142) substituents in quite good yields (28 -75%, Table 5) [86,87,89]. Note, however, that structures of the target compounds were decided on the basis of only UV-vis and IR spectra as well as elemental analysis, while NMR and mass spectra of these complexes were not reported.…”

Section: Phthalocyanine-metal-phthalocyanine Complexesmentioning

confidence: 99%

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Historic overview and new developments in synthetic methods for preparation of the rare-earth tetrapyrrolic complexes

Pushkarev

Tomilova

Nemykin

2016

Coordination Chemistry Reviews

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New developments as well as a historic overview on synthetic strategies for preparation of the rare-earth complexes with porphyrins, phthalocyanines, naphthalocyanines, tetraazaporphyrins, and related systems are discussed in detail with emphasis on selective synthetic pathways for preparation of single-, double, and triple-decker architectures. 6 IntroductionAfter their discovery almost 100 years ago, phthalocyanines (Pcs) were predominantly investigated because of their industrial applications as dyes, pigments, and catalysts [1][2][3].Similarly, historically, porphyrins (Pors) were intensively studied because of their importance in mimicking biologically relevant atom-and electron-transfer processes as well as light-harvesting mechanisms associated with living cells [4][5][6]. In addition, porphyrins, phthalocyanines, and their analogues were found to be useful in applications such as redox-driven fluorescence markers and biomarkers, light-harvesting antennas for organic photovoltaics and dye sensitized solar cells, charge carriers for copiers and printers, materials for molecular electronics, as well as redoxactive components in environmental, biological, and industrial sensors as well as active components in photodynamic therapy (PDT) and boron neutron therapy (BNT) of cancer [7][8][9][10][11][12][13][14][15][16][17][18][19].In their initial attempts, researchers focused on rich coordination, redox, and magnetic properties of the metal-free, main-group, and especially transition-metal porphyrinoids. It was soon realized, however, that the rare-earth ions can form unusual systems when coupled with the phthalocyanine ligand.The first rare-earth Pcs were reported by Russian scientists Kirin and Moskalev in 1965 [20]. Kirin and Moskalev also pointed out that because of the large ionic radii and high coordination numbers of the rare-earth ions, the formation of the double-decker rare-earth phthalocyanine compounds could be achieved under specific reaction conditions [20,21]. During the next 50 years, it was confirmed that rare-earth ions are capable of the formation of phthalocyanine single-, double, and triple-decker complexes and their analogues [22][23][24][25][26][27][28][29][30][31][32][33]. One of the interesting recent discoveries was the preparation and characterization of heteronuclear (rareearth / cadmium) multiple-decker complexes, which contain up to six Pc ligands [34][35][36][37][38][39][40][41][42].

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Section: Template Synthesis From Phthalogensmentioning

confidence: 99%