Synthesis of Tri-Arm Star Shaped 1, 3, 5-Triazines Catalyzed by 1,5,7-TRIAZABICYCLO[4.4.0] Dec-5-Ene (Tbd)

Abstract

Facile solution method for the synthesis of tri-arm star shaped 1,3,5-triazines was developed using 1,5,7-Triazabicyclo[4.4.0]dec-5-ene (TBD) by reaction of cyanuric chloride with O-nucleophiles.

Research on the catalytic activity of MNP-[Dop-OH]-CuBr2 nanocomposites: novel and stable reusable nanocatalysts for the synthesis of 1,3,5-triazine derivatives

“…All products are known and the physical properties of the corresponding products are in good agreement with the reported samples . [20][21][22][23][24] Based on the literature search, 24 we present a tentative mechanism for the synthesis of 1,3,5-triazine derivatives via the oxidative coupling reaction of amidine hydrochlorides and alcohols catalyzed by MNP-[Dop-OH]-CuBr 2 nanocomposites under air conditions in Scheme 2.…”

“…All products are known and the physical properties of the corresponding products are in good agreement with the reported samples . 20–24…”

“…1. [20][21][22] Substituted 1,3,5triazines are usually synthesized in two different ways. The classic method is based on the nucleophilic substitution of chlorine atoms in the starting material 2,4,6-trichloro-1,3,5triazine, i.e., cyanuric chloride.…”