Synthesis of triple halide-bridged arene complexes of ruthenium(II) and osmium(II)

Synthesis, Structure and Reactivity of Homo‐ and Heterobimetallic Complexes of the General Formula [Cp*Ru(μ‐Cl)3ML] [LM = (arene)Ru, Cp*Rh, Cp*Ir]

“…+ is obtained in equilibrium with the two homobimetallic starting materials. [21] We have previously shown that the triply bridged complex [(dcypb)(N 2 )Ru(µ-Cl) 3 [9b] Taken together, these results point to the fact that [L n Ru(µ-Cl) 3 MLЈ n ] complexes are generally very labile, despite their apparent thermodynamic stability.…”

Highly selective low-temperature hydrogenation of furfuryl alcohol to tetrahydrofurfuryl alcohol catalysed by hectorite-supported ruthenium nanoparticles

“…The sodium cation exchange capacity, determined according to the method of Lagaly [21], was found to be 104 mEq per 100 g. The dimeric complex [(C 6 H 6 ) 2 RuCl 2 ] 2 was synthesized following the procedure reported by Arthur and Stephenson [22].…”

X-ray crystallographic study of two dinuclear triply-bridged p-cymene osmium complexes

“…In 1981, the synthesis of the dinuclear complex [Os(pcymene)Cl 2 ] 2 opened the door to the formation of pcymene osmium derivatives [7]. From this dinuclear arene osmium compound, a variety of complexes were synthesised [2,[8][9][10][11][12][13][14][15][16][17][18][19], among them the cationic species [Os 2 (pcymene) 2 …”