Synthesis of two nickel (II) complexes bearing pyrrolide-imine ligand and their catalytic effects on thermal decomposition of ammonium perchlorate

Ferrocene and [3]ferrocenophane-based β-diketonato copper(ii) and zinc(ii) complexes: synthesis, crystal structure, electrochemistry and catalytic effect on thermal decomposition of ammonium perchlorate

“…The result showed that the redox potentials of b-diketone ligands and their complexes were slightly inuenced by the scan rate in a range from 10 to 300 mV s À1 , and both the anodic and cathodic peak currents are linear to the square root of scan rates, indicating a diffusion-controlled process. 25…”

“…This implies that the complexes can advance the decomposition temperature of AP as well as narrow signicantly the decomposition temperature range of AP. 25 So the Cu complex is a more effective catalyst than the Zn complex, which may attribute to the enhanced catalytic performance of Cu oxide compared with Zn oxide to the thermal decomposition of AP. These oxides produced by the thermal decomposition of the complexes are the active species during the combustion of propellants.…”

“…Recently, transition-metal complexes containing ferrocenyl attracted signicant interest, due to their excellent thermal stability and catalytic properties. [25][26][27][28][29] Among these, the transition metal complexes of ferrocene-containing b-diketones as polynuclear ferrocenyl derivatives, widely used in conjugate chemistry, 30 electrochemical studies 31 and medicinal chemistry 32 etc. are supposed to be potentially high BR catalysts due to containing large polar carbonyl and metal atoms.…”

Synthesis, Anti‐migration and Catalytic Effect of Ferrocene Azine Derivatives on the Thermal Decomposition of Ammonia Perchlorate

“…[2] In order to overcome the disadvantage of easy migration, many scholars have carried out a lot of modifications on ferrocene BRCs, for example, preparing ferrocene ionic compounds [3,4] or introducing polar groups [5][6][7] into molecules to reduce the volatility and mobility of ferrocene BRCs by increasing the van der Waals force between propellant components and ferrocene BRCs; or introducing active groups (such as amino, hydroxyl, silicon hydrogen bond, etc.) into the molecules of BRCs, which can participate in crosslinking during propellant curing [8,9] so as to reduce their mobility; designing binuclear or polynuclear ferrocene derivatives [10][11][12] to reduce their mobility by increasing the molecular weight of the catalyst to increase the vapor pressure; preparing polymers [13][14][15] or complexes [16][17][18] containing ferrocenyl groups, etc.…”

Synthesis of Energetic Complexes [Co(en)(H2BTI)2]2 ⋅ en, [Cu2(en)2(HBTI)2]2 and Catalytic Study on Thermal Decomposition of Ammonium Perchlorate

“…Therefore, how to find certain energetic burning catalysts to solve the problem is widely investigated. In recent years, the metalorganic energetic compound as catalysts is becoming the main research direction [16][17][18][19][20][21][22], because the high energetic complex can effectively promote the thermal decomposition of combustion component completely, improve the burning rate and specific impulse of the solid propellant, and increase the energy of composite propellants via the contribution of the heat of energetic ligands.…”