“…The efficiency of ZnO homojunctions has been limited due to the low carrier concentration, instability and low mobility of the holes in ZnO [7,8]. So, the growth of n-ZnO nanostructures on other p-type semiconductors such as Si [9], GaN [10][11][12], SiC [13][14][15][16] and NiO [17][18][19] can provide alternative way to realize ZnO-based p-n heterojunctions. To the best of our knowledge, few researchers have used p-GaAs as a substrate for ZnO-based LEDs [20,21], and there have been no detailed investigations reported about use of an intermediate layer to improve the optical and electrical properties of n-ZnO nanorods/p-GaAs heterojunction.…”