Synthesis of ZnO Tetrapods Using Atmospheric Plasma Jet and Their Size-Dependent Photosensing Properties

Abstract

We report the synthesis of ZnO tetrapods using an atmospheric-pressure microwave plasma jet system, and analyze their size-dependent photosensing properties. The sizes of the synthesized ZnO tetrapods are controlled by changing the applied plasma power and the distances of their collection sites from the plasma-generation region. The results of high-magnification transmission electron microscopy, X-ray diffractometry, and Raman spectroscopy indicate that the synthesized ZnO tetrapods exhibit high crystallinity. In general, the size of ZnO tetrapods increases as the plasma power and distance from the plasma-generation region increase. A photosensing device is fabricated for comparative characterization by dispersing the synthesized ZnO tetrapods in deionized water and spray coating them. The results of the sensing characterization using ultraviolet light illumination show that larger ZnO tetrapods increase the photocurrent, improve the sensitivity, and reduce the sheet resistance of the device.

Facile Fabrication of Flexible Photosensors Using Zinc Oxide Tetrapods and Their Ultraviolet Response Evaluation

“…The positively charged surface (+𝑐) was likely to be terminated by Zn atoms, resulting in the growth of legs along the four [0001] directions to form a wurtzite structure [14][15][16][17][18]. The dependence of the size on the photosensing characteristics were also evaluated based on the collection site and power applied in the APMP system [19].…”