Synthesis of β‐Amino Alcohols from Aromatic Amines and Alkylene Carbonates Using Na‐Y Zeolite Catalyst.

Shivarkar, Anandkumar B.; Gupte, Sunil P.; Chaudhari, Raghunath V.

doi:10.1002/chin.200640068

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2023

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“…Vinylene carbonate is an inexpensive electron-deficient olefin; nevertheless, the nucleophilic additions between indoles with vinylene carbonate for the preparation of indolyl-containing ethylene carbonates have not been reported. Furthermore, indolyl-containing ethylene carbonates can undergo further transformation so as to obtain structurally diverse indolyl-containing skeletons [37][38][39][40][41].…”

Section: Introductionmentioning

confidence: 99%

Base-Catalyzed Nucleophilic Addition Reaction of Indoles with Vinylene Carbonate: An Approach to Synthesize 4-Indolyl-1,3-dioxolanones

Chen,

Zhou,

Bao

2023

Molecules

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The N-functionalized indole is a privileged structural framework in a wide range of bioactive molecules. The nucleophilic addition between indoles with vinylene carbonate proceeded smoothly in the presence of K2CO3 as the catalyst to produce novel indolyl-containing skeletons and 4-indolyl-1,3-dioxolanones in satisfactory to excellent yields (up to >97% yield). Various synthetically useful functional groups, such as halogen atoms, cyano, nitro, and methoxycarbonyl groups, remained intact during the regioselective N-H addition reactions. The developed catalytic system also could accommodate 2-naphthalenol to achieve the target O-H additive product in good yield.

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Section: Introductionmentioning

confidence: 99%

Base-Catalyzed Nucleophilic Addition Reaction of Indoles with Vinylene Carbonate: An Approach to Synthesize 4-Indolyl-1,3-dioxolanones

Chen,

Zhou,

Bao

2023

Molecules

View full text Add to dashboard Cite

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Synthesis of β‐Amino Alcohols from Aromatic Amines and Alkylene Carbonates Using Na‐Y Zeolite Catalyst.

Abstract: ChemInform is a weekly Abstracting Service, delivering concise information at a glance that was extracted from about 200 leading journals. To access a ChemInform Abstract, please click on HTML or PDF.

Cited by 1 publication

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Base-Catalyzed Nucleophilic Addition Reaction of Indoles with Vinylene Carbonate: An Approach to Synthesize 4-Indolyl-1,3-dioxolanones

Base-Catalyzed Nucleophilic Addition Reaction of Indoles with Vinylene Carbonate: An Approach to Synthesize 4-Indolyl-1,3-dioxolanones

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