2007
DOI: 10.1021/jp067475i
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Synthesis, Optical Properties, and Surface Enhanced Raman Scattering of Silver Nanoparticles in Nonaqueous Methanol Reverse Micelles

Abstract: In the present work, we have reported the in situ synthesis of metal nanoparticles in the polar core of nonaqueous methanol reverse micelles. We have obtained both monodisperse and partially polydisperse silver nanoparticles at different condition and time in the polar core of methanol reverse micelles using sodium borohydride as a reducing agent and the confined cavity and the charged surfactant (sodium bis(2-ethylhexyl)sulfosuccinate-(AOT)) as a stabilizing agent in the presence of air. In the initial stage … Show more

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Cited by 68 publications
(44 citation statements)
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“…Among metal/polymer composites, silver composites have found important applications in material technologies like optical materials, 24 catalytic systems, antibacterial materials, 25,26 chemical nanosensors, and surface-enhanced Raman scattering (SERS). 27 However, the most significant challenge encountered in preparing silver/polymer nanoparticle encapsulation is that the nanoparticles cannot be dispersed in polymer matrix at the nano level by conventional techniques because the surface energies of tiny silver particles are very high, and these particles tend to agglomerate during mixing. For application in optoelectronics and electronics, the precise control of particle size and their uniform distribution within the polymer are key technologies based on nanoparticles in polymers.…”
Section: 15mentioning
confidence: 99%
“…Among metal/polymer composites, silver composites have found important applications in material technologies like optical materials, 24 catalytic systems, antibacterial materials, 25,26 chemical nanosensors, and surface-enhanced Raman scattering (SERS). 27 However, the most significant challenge encountered in preparing silver/polymer nanoparticle encapsulation is that the nanoparticles cannot be dispersed in polymer matrix at the nano level by conventional techniques because the surface energies of tiny silver particles are very high, and these particles tend to agglomerate during mixing. For application in optoelectronics and electronics, the precise control of particle size and their uniform distribution within the polymer are key technologies based on nanoparticles in polymers.…”
Section: 15mentioning
confidence: 99%
“…These special properties have been applied in various fields ranging from microelectronics to biomedical science. [8] Au nanoparticles with interesting morphologies have been synthesised through various methods, such as chemical, [9][10][11][12] electrochemical, [13] sonochemical, [14] green synthesis, [15,16] conventional polyol process, [17,18] and spraypyrolysis method, [19] g-irradiation route, [20] ultraviolet irradiation, [21] template approach, [22][23][24][25] etc. Growth of nanostructures having different morphologies can result in the modification of its physical properties and improvement in performance characteristics.…”
Section: Introductionmentioning
confidence: 99%
“…NPs synthesized using this technique include metals (e.g. Ag) [17] , bimetallics (e.g. Au/Pd) [18] alloys (e.g.…”
Section: Introductionmentioning
confidence: 99%