2004
DOI: 10.1016/j.poly.2003.09.017
|View full text |Cite
|
Sign up to set email alerts
|

Synthesis, structural characterisation and thermal decomposition of [{Pt(dppf)(2-SPy)}{BF4}] (dppf=1,1′-bisdiphenylphosfinoferrocene and 2-SPy=2-mercaptopyridine) – a source for a Fe–Pt containing alloy

Help me understand this report

Search citation statements

Order By: Relevance

Paper Sections

Select...
1
1
1
1

Citation Types

0
4
0

Year Published

2006
2006
2023
2023

Publication Types

Select...
8

Relationship

0
8

Authors

Journals

citations
Cited by 18 publications
(4 citation statements)
references
References 18 publications
0
4
0
Order By: Relevance
“…The interaction of such ligands with heavy metals, such as gold and platinum, is of special interest because of their antitumor properties with the potential to develop metal-based drugs. To this end, some papers involving platinum (II or IV) and gold (I) complexes of these ligands with tertiary phosphines as co-lignads have been reported in the literature [5][6][7][8][9][10].…”
Section: Introductionmentioning
confidence: 99%
“…The interaction of such ligands with heavy metals, such as gold and platinum, is of special interest because of their antitumor properties with the potential to develop metal-based drugs. To this end, some papers involving platinum (II or IV) and gold (I) complexes of these ligands with tertiary phosphines as co-lignads have been reported in the literature [5][6][7][8][9][10].…”
Section: Introductionmentioning
confidence: 99%
“…The platinum­(II) centers in both fragments lie in distorted-square-planar environments. The P(1)–Pt(1)–P(2) bond angle is large, 118.44(3)° ( 6 ) and 117.11(4)° ( 7 ), and the small S(1)–Pt(2)–S(2) bond angle in 6 , 73.91(3)°, and S–Pt(2)–N(1) angle in 7 , 68.91(10)°, are the expected values for the bite angles of the chelating xanthogenate and pyrimidine-2-thiolate ligands. The dihedral angles between the best coordination planes of the two Pt atoms in each complex are 59.56(3) and 62.62(3)°, respectively.…”
Section: Resultsmentioning
confidence: 66%
“…The third step of thermal decomposition take place over the temperature range of Table 4 The experimental and simulated molar heat capacities of DPFEB 1000-1120 K with the weight loss of about 2.9%. When it was heated in nitrogen atmosphere, DPFEB experienced a process of carbonization and incineration, so that the residue should be composed of carbon and iron phosphine [31].…”
Section: Tg Analysismentioning
confidence: 99%