2019
DOI: 10.1016/j.materresbull.2019.110505
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Synthesis, structural characterization and electrical conduction mechanism of the new organic–inorganic complex: ([(C3H7)4N]FeCl4)

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Cited by 27 publications
(10 citation statements)
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“…The frequency response of the materials has further been analysed.in order to determine the dominant AC conduction mechanism, The increase of with decreasing temperature is consistent with the correlated barrier hopping (CBH) model in which the relaxation process is by hopping of charges between pair of localised states [23]. Similar conduction mechanism is reported for 8 mm in diameter and 1.1 mm in thickness of newly synthesized inorganic-organic tetrapropylammonium tetrachloferrate nanocomposite at temperature between 313K and 388 K over the frequency range from 10 3 Hz to 10 7 Hz [24].…”
Section: Resultssupporting
confidence: 78%
“…The frequency response of the materials has further been analysed.in order to determine the dominant AC conduction mechanism, The increase of with decreasing temperature is consistent with the correlated barrier hopping (CBH) model in which the relaxation process is by hopping of charges between pair of localised states [23]. Similar conduction mechanism is reported for 8 mm in diameter and 1.1 mm in thickness of newly synthesized inorganic-organic tetrapropylammonium tetrachloferrate nanocomposite at temperature between 313K and 388 K over the frequency range from 10 3 Hz to 10 7 Hz [24].…”
Section: Resultssupporting
confidence: 78%
“…For both the compounds, the value of s ( T ) first remains constant, and then decreases with increasing temperature (Figure c). This kind of temperature behavior of s ( T ) reveals that the conduction mechanism is a correlated barrier hopping (CBH) type as reported in many other compounds. , The decreasing value of s ( T ) with increasing temperature means that the interaction among the mobile ions increases with increasing temperature.…”
Section: Resultssupporting
confidence: 65%
“…From the shape of these spectra, it can be understood the presence of a single semi-circular arc at each temperature, which confirms the grain contribution in this material. 23 Moreover, the shows that the radius of the corresponding semicircular arcs decreased inversely with temperature, which reveals that the a conductivity improvement and thus more dielectric loss. 24 The material has thus a semiconductor behavior.…”
Section: Resultsmentioning
confidence: 88%