Synthesis, structural characterization, and reactivity toward weak, protic electrophiles of di-.mu.-hydroxytetrakis(pentafluorophenyl)dipalladate(2-)

López, Gregorio; Ruiz, José; Garcı́a, Gabriel; Vicente, Consuelo; Casabo, J.; Molins, Elı́es; Miravitlles, C.

doi:10.1021/ic00012a008

Cited by 88 publications

(68 citation statements)

References 2 publications

Supporting

Mentioning

Contrasting

Order By: Relevance

“…The 1 H NMR of complex 1 in D 2 O showed an additional signal at 2.07 ppm corresponding to the acetonitrile molecules; this shift is very similar to the one reported for the free acetonitrile in D 2 O (2.06 ppm) [25] [5,26]. Unfortunely, attempts to acquire the 1 H NMR spectra of complex 2 in CDCl 3 were unsuccessful due to its very low solubility.…”

Section: Synthesis Of Palladium Phenanthroline Complexessupporting

confidence: 75%

Palladium(II) complexes of 1,10-phenanthroline: Synthesis and X-ray crystal structure determination

Adrian¹,

Broker²,

Tiekink³

et al. 2008

Inorganica Chimica Acta

View full text Add to dashboard Cite

Two palladium(II) complexes, [Pd(phen) , in acetonitrile and water, respectively. The structures of both complexes are based on a Pd(phen) 2+ metal core, with two acetonitrile molecules binding in a monodentate fashion in complex 1 and two hydroxo bridges holding together two cores to form a dimer in complex 2. Additionally, both complexes present a hydrogen bonded 3-D network involving the triflate anions in 1, and water and triflate anions in 2. Both complexes have been characterized by infrared and 1 H NMR spectroscopy and their crystal structures determined by Xray crystallography.

show abstract

Section: Synthesis Of Palladium Phenanthroline Complexessupporting

confidence: 75%

Palladium(II) complexes of 1,10-phenanthroline: Synthesis and X-ray crystal structure determination

Adrian¹,

Broker²,

Tiekink³

et al. 2008

Inorganica Chimica Acta

View full text Add to dashboard Cite

show abstract

“…For instance, if the metal complex contains ligands (X) such as alkyl, hydrido, alkoxido, amido, etc., its reaction with relatively acidic N-H groups such as those of azoles can afford azolatometal complexes upon elimination of HX (HX = alkane, dihydrogen, alcohol, amine, etc). [20] A similar reactivity has been encountered for some η 5 -cyclopentadienyl complexes. [21] Even with less reactive ligands, such as chlorido, elimination of hydrogen chloride can occur, which is favored by its volatility.…”

Section: Supramolecular Behavior Of Free Pyrazolessupporting

confidence: 64%

Pyrazole Complexes and Supramolecular Chemistry

2009

View full text Add to dashboard Cite

This Microreview deals with the supramolecular chemistry of pyrazole metal complexes, in particular, complexes of pyrazoles with a nonsubstituted N–H group, which are able to engage in hydrogen bonding. The most pertinent general features of pyrazoles, in comparison with other heterocycles that are also popular ligands, and some aspects of the supramolecular chemistry of free pyrazoles are also included. In addition to the general supramolecular chemistry of pyrazole complexes, sections of this Microreview are devoted to liquid crystals, self‐assembled species, and hosts for anions. (© Wiley‐VCH Verlag GmbH & Co. KGaA, 69451 Weinheim, Germany, 2009)

show abstract

“…-Organometallic binuclear nickel, palladium, and platinum complexes of the types [M,R4(p-OH)2]2-(R = C6F5, M = Ni [l], Pd [2], or Pt [3]; R = C6C15, M = Pd 141 or Pt [3] [4][12], thiols [13] aromatic alcohols [14], or malononitrile [15]) and mononuclear anionic complexes [MR,X]-(HX = P-diketones, heterocyclic thiones [16] or P-ketoimines [17]) by reaction with the corresponding protic electrophile. The nickel complex [Niz(c6F5)4(p-OH),]2 -is an efficient catalyst for the cyclotrimerization of malononitrile to 4,6-diamino-2-(cyanomethyl)pyridine-3,5-dicarbonitrile [15].…”

mentioning

confidence: 99%

Organonickel(II) Complexes with Anionic N‐Donor Ligands. Hydration of coordinated nitriles at a nickel(II) site

Sánchez

Ruiz

Garcia

et al. 1997

Helvetica Chimica Acta

View full text Add to dashboard Cite

The hydroxo complex (Bu4N)2[Ni2(C6F5)4(μ‐OH)2]reacts with 2,3,4,5,6‐pentafluoro benzenamine (C6F5‐NH2), 1,3‐diaryltriaz‐1‐enes (ArNHN=NAr, Ar = Ph, 4‐MeC6H4, 4‐MeOC6H4), 7‐aza‐1H‐indole (= 1H‐pyrrolo[2.3‐b]pyridine; Hazind), N‐phenylpyridin‐2‐amine(pyNHPh), and N‐phenylpyridine‐2‐carboxamide (py‐CONHPh) at room temperature in acetone to give the binuclear complexes (Bu4N)2[Ni2(C6F5)4(μ‐C6F5NH)2] (1) and (Bu4N)2[{Ni(C6F5)2} 2(μ‐OH)(μ‐azind)] (2) and the mononuclear complexes Bu4N[Ni(C6F5)2(ArN3Ar)] (3–5), Bu4N[Ni(C6F5)2(pyNPh)] (6), and Bu4N[Ni(C6F5)2(pyCONPh)] (7). The hydroxo.complex (Bu4N)2[{Ni(C6F5)2‐(μ‐OH)}2] promotes the nucleophilic addition of water to pyridine‐2‐carbonitrile, 2‐aminoacetonitrile, and 2‐(dimethylamino)acetonitrile, and complexes 8–10 containing pyridine‐2‐carboxamidato, 2‐aminoacetamidato and 2‐(dimethylamino)acetamidato ligands are formed. Analytical (C, H, N) and spectroscopic (IR, 1H and 19F‐NMR, and FAB‐MS) data were used for structural assignments. A single‐crystal X‐ray diffraction study of (Bu4N)2[{Ni(C6F5)2}2(μ‐OH)(μ‐azind)] (2) established the binuclear nature of the anion; the two Ni‐atoms are bridged by an OH group and a 7‐aza‐7H‐indol‐7‐yl group, but the central NiONiNCN ring is not planar, the dihedral angle between the NiONi and NiNCNNi planes being 84.4°.

show abstract

Synthesis, structural characterization, and reactivity toward weak, protic electrophiles of di-.mu.-hydroxytetrakis(pentafluorophenyl)dipalladate(2-)

Cited by 88 publications

References 2 publications

Palladium(II) complexes of 1,10-phenanthroline: Synthesis and X-ray crystal structure determination

Palladium(II) complexes of 1,10-phenanthroline: Synthesis and X-ray crystal structure determination

Pyrazole Complexes and Supramolecular Chemistry

Organonickel(II) Complexes with Anionic N‐Donor Ligands. Hydration of coordinated nitriles at a nickel(II) site

Contact Info

Product

Resources

About