Synthesis, structural characterization and solvent effect of copper(II) complexes with a variational multidentate Salen-type ligand with bisoxime groups

Crystal structure of (E)-1-(4-(((E)-3,5-dibromo-2-hydroxybenzylidene)amino)phenyl)ethan-1-one O-methyl oxime, C17H16Br2N2O2

“…Much attentions have recently been paid to the synthesis and crystal structure of oximes and their derivatives [1][2][3][4]. These compounds are an important class of organic compounds because of their applications in many elds of organic, biological, analytical chemistry [5,6] and material science [7].…”

“…The title compound was prepared by modi cation of the reported method [1][2][3][4]. To an ethanol solution (5 mL) of 4-amino acetophenone ethoxy oxime (178.0 mg, 1 mmol) was added an ethanol solution (5 mL) of 3,5-dibromosalicyladehyde (279.9 mg, 1.0 mmol).…”

Crystal structure of 2-(3,5-dichloro-2-hydroxyphenyl)-4-methyl- 1,2-dihydroquinazoline 3-oxide, C15H12Cl2N2O2

“…The oxime-type compounds are potentially multidentate ligands [1,2] because they can accommodate one, two or more transition metal centers and form metal complexes with interesting properties [3][4][5][6], such as excellent catalytic activity for epoxidation or aziridination [7], models of reaction centers of metalloenzymes [8], nonlinear optical materials [9],and for molecular recognition and biological activity [10]. The title crystal structure is only built up by the C 15 H 12 Cl 2 N 2 O 2 molecules, in which all bond lengths are in normalranges.…”

Crystal structure of 2,2'-(1,2-ethylenedioxy)bisbenzaldehyde O,O'-dimethyldioxime, C18H20N2O4

“…Much attention has recently been paid to the synthesis and crystal structure of oxime-type compounds and their derivatives [3][4][5][6]. These compounds can accommodate one, two or more metal centers and form homo-and heteronuclear metal complexes serving as catalysts [ 7], models of reaction centers of metalloenzymes [8], nonlinear optical materials [9] and molecular recognition and biological agents [10].…”