Synthesis, structural elucidation, and catalytic evaluation of glucopyranosylamine-derived Mo(VI) complex

Parikh, Anuvasita; Mishra, Santosh Kumar; Madduluri, Vimal Kumar; Parikh, Parmeshthi; Rangan, Krishnan; Sah, Ajay K.

doi:10.1016/j.molstruc.2023.136858

Journal of Molecular Structure

2024

DOI: 10.1016/j.molstruc.2023.136858

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Synthesis, structural elucidation, and catalytic evaluation of glucopyranosylamine-derived Mo(VI) complex

Anuvasita Parikh,

Santosh Kumar Mishra,

Vimal Kumar Madduluri

et al.

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2024

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Cited by 3 publications

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Glucoconjugated Dinuclear Copper(II) Complex: An Efficient Catalyst for Stereoselective Synthesis of Trisubstituted Propargylamines via Solvent‐free A³ Coupling Reaction

Kumar Mishra,

Parikh,

Parikh

et al. 2024

ChemPlusChem

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Development of catalytic systems using nontoxic natural precursors is the need of the era, and along this line, we have synthesized a new D‐glucose derived ligand (4,6‐O‐ethylidene‐N‐(2‐hydroxy‐4‐(octyloxy)benzylidene)‐β‐D‐glucopyranosylamine) and its dinuclear copper(II) complex. The molecular structure of the complex has been established by single‐crystal X‐ray diffraction studies and detailed noncovalent intermolecular interactions present in it has been explored by Hirshfeld surface analysis. Further, the complex has been used as catalyst in the enantioselective (87‐99% ee) synthesis of propargylamines in good to excellent yield (82‐95%) via aldehyde‐amines‐alkynes (A3) coupling reaction under solvent‐free condition. The formation of aminal intermediate during the reaction has been confirmed by 1H‐NMR and single‐crystal X‐ray diffraction studies. The catalytic system is reusable without any appreciable loss in the enantioselectivity or product yield.

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Glucoconjugated Dinuclear Copper(II) Complex: An Efficient Catalyst for Stereoselective Synthesis of Trisubstituted Propargylamines via Solvent‐free A³ Coupling Reaction

Kumar Mishra,

Parikh,

Parikh

et al. 2024

ChemPlusChem

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Pyridine hydrazide glycoconjugate-based gelators: Facile synthesis and exploring their application in iodide sensing

Pradhan,

Hussain,

Małecki

et al. 2024

Journal of Molecular Liquids

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Synthesis, crystal structure and anticancer activity of 4‑chloro-2-methoxybenzoic acid transition metal complexes

Zhang,

Yin,

Zhang

et al. 2024

Journal of Molecular Structure

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Synthesis, structural elucidation, and catalytic evaluation of glucopyranosylamine-derived Mo(VI) complex

Cited by 3 publications

References 31 publications

Glucoconjugated Dinuclear Copper(II) Complex: An Efficient Catalyst for Stereoselective Synthesis of Trisubstituted Propargylamines via Solvent‐free A³ Coupling Reaction

Glucoconjugated Dinuclear Copper(II) Complex: An Efficient Catalyst for Stereoselective Synthesis of Trisubstituted Propargylamines via Solvent‐free A³ Coupling Reaction

Pyridine hydrazide glycoconjugate-based gelators: Facile synthesis and exploring their application in iodide sensing

Synthesis, crystal structure and anticancer activity of 4‑chloro-2-methoxybenzoic acid transition metal complexes

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Synthesis, structural elucidation, and catalytic evaluation of glucopyranosylamine-derived Mo(VI) complex

Cited by 3 publications

References 31 publications

Glucoconjugated Dinuclear Copper(II) Complex: An Efficient Catalyst for Stereoselective Synthesis of Trisubstituted Propargylamines via Solvent‐free A3 Coupling Reaction

Glucoconjugated Dinuclear Copper(II) Complex: An Efficient Catalyst for Stereoselective Synthesis of Trisubstituted Propargylamines via Solvent‐free A3 Coupling Reaction

Pyridine hydrazide glycoconjugate-based gelators: Facile synthesis and exploring their application in iodide sensing

Synthesis, crystal structure and anticancer activity of 4‑chloro-2-methoxybenzoic acid transition metal complexes

Contact Info

Product

Resources

About

Glucoconjugated Dinuclear Copper(II) Complex: An Efficient Catalyst for Stereoselective Synthesis of Trisubstituted Propargylamines via Solvent‐free A³ Coupling Reaction

Glucoconjugated Dinuclear Copper(II) Complex: An Efficient Catalyst for Stereoselective Synthesis of Trisubstituted Propargylamines via Solvent‐free A³ Coupling Reaction