Synthesis, structure anatomy, and catalytic properties of Ag<sub>14</sub>Cu<sub>2</sub> nanoclusters co-protected by alkynyl and phosphine ligands

Shen, Quanli; Cong, Xuzi; Chen, Leyi; Wang, Lei; Liu, Yonggang; Wang, Likai; Tang, Zhenghua

doi:10.1039/d3dt02838k

Dalton Trans.

2023

DOI: 10.1039/d3dt02838k

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Synthesis, structure anatomy, and catalytic properties of Ag₁₄Cu₂ nanoclusters co-protected by alkynyl and phosphine ligands

Quanli Shen,

Xuzi Cong,

Leyi Chen

et al.

Abstract: We report the synthesis, structure anatomy, and catalytic properties of Ag14Cu2(C≡CArF)14(PPh3)4 (C≡CArF: 3, 5-Bis(trifluoromethyl)phenylacetylene) nanoclusters, denoted as Ag14Cu2. Ag14Cu2 has a robust electronic structure with two free valence electrons, and...

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Cited by 4 publications

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Advancing electrochemical CO₂ reduction with group 11 metal nanoclusters for renewable energy solutions

Biswas,

Shingyouchi,

Ogami

et al. 2024

EcoEnergy

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Understanding the intricate relationship between structure and properties is paramount in distinguishing nanocluster (NC) materials from their counterparts. Despite the progress in synthesizing new NCs, the sluggish exploration of their potential applications persists due to the difficulty in stabilizing these materials. However, recent investigations have unveiled their remarkable efficacy as catalysts in electrochemical CO2 reduction reactions, surpassing traditional materials. This discovery, addressing urgent global concerns, has quickly drawn significant attention to this field, leading to its rapid expansion. Hence, there is an urgent need to outline this research landscape and pinpoint effective strategies, marking a significant advancement. In this context, our endeavor is dedicated to offering researchers a thorough understanding of recently synthesized NC materials. We aim to elucidate their distinct structural architectures and associated properties essential for catalyst design. We envision that this systematic review will serve as a guiding beacon for future research endeavors in this burgeoning field.

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Advancing electrochemical CO₂ reduction with group 11 metal nanoclusters for renewable energy solutions

Biswas,

Shingyouchi,

Ogami

et al. 2024

EcoEnergy

View full text Add to dashboard Cite

show abstract

Alkynyl ligand for preparing atomically precise metal nanoclusters: Structure enrichment, property regulation, and functionality enhancement

Liu,

Qin

et al. 2024

Chinese Journal of Structural Chemistry

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Self-assembled infinite silver cluster with atomic precision as a scalable catalyst for CO₂-electroreduction under industry-relevant reaction rates

Curet,

Lafargue dit-Hauret,

Benet-Buchholz

et al. 2025

EES. Catal.

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Synthesis, structure anatomy, and catalytic properties of Ag₁₄Cu₂ nanoclusters co-protected by alkynyl and phosphine ligands

Abstract: We report the synthesis, structure anatomy, and catalytic properties of Ag14Cu2(C≡CArF)14(PPh3)4 (C≡CArF: 3, 5-Bis(trifluoromethyl)phenylacetylene) nanoclusters, denoted as Ag14Cu2. Ag14Cu2 has a robust electronic structure with two free valence electrons, and...

Cited by 4 publications

References 49 publications

Advancing electrochemical CO₂ reduction with group 11 metal nanoclusters for renewable energy solutions

Advancing electrochemical CO₂ reduction with group 11 metal nanoclusters for renewable energy solutions

Alkynyl ligand for preparing atomically precise metal nanoclusters: Structure enrichment, property regulation, and functionality enhancement

Self-assembled infinite silver cluster with atomic precision as a scalable catalyst for CO₂-electroreduction under industry-relevant reaction rates

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Synthesis, structure anatomy, and catalytic properties of Ag14Cu2 nanoclusters co-protected by alkynyl and phosphine ligands

Abstract: We report the synthesis, structure anatomy, and catalytic properties of Ag14Cu2(C≡CArF)14(PPh3)4 (C≡CArF: 3, 5-Bis(trifluoromethyl)phenylacetylene) nanoclusters, denoted as Ag14Cu2. Ag14Cu2 has a robust electronic structure with two free valence electrons, and...

Cited by 4 publications

References 49 publications

Advancing electrochemical CO2 reduction with group 11 metal nanoclusters for renewable energy solutions

Advancing electrochemical CO2 reduction with group 11 metal nanoclusters for renewable energy solutions

Alkynyl ligand for preparing atomically precise metal nanoclusters: Structure enrichment, property regulation, and functionality enhancement

Self-assembled infinite silver cluster with atomic precision as a scalable catalyst for CO2-electroreduction under industry-relevant reaction rates

Contact Info

Product

Resources

About

Synthesis, structure anatomy, and catalytic properties of Ag₁₄Cu₂ nanoclusters co-protected by alkynyl and phosphine ligands

Advancing electrochemical CO₂ reduction with group 11 metal nanoclusters for renewable energy solutions

Advancing electrochemical CO₂ reduction with group 11 metal nanoclusters for renewable energy solutions

Self-assembled infinite silver cluster with atomic precision as a scalable catalyst for CO₂-electroreduction under industry-relevant reaction rates