Synthesis, structure and characterization of 1-D polymer {[Sr(CHZ)2(ClO4)]ClO4}n: a new concept for designing primary explosives

An overview of the current status of coordination polymers and metal-organic frameworks (MOFs) pertaining to the field of energetic materials is provided. The explosive applications of MOFs are discussed from two aspects: one for detection of explosives, and the other for explosive desensitization. By virtue of their adjustable pore/cage sizes, high surface area, tunable functional sites, and rich host-guest chemistry, MOFs have emerged as promising candidates for both explosive sensing and desensitization. The challenges and perspectives in these two areas are thoroughly discussed, and the processing methods for practical applications are also discussed briefly.

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Explosives in the Cage: Metal–Organic Frameworks for High‐Energy Materials Sensing and Desensitization

Wang

Feng

et al. 2017

Advanced Materials

153

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Synthesis and Properties of [Ba(CHZ)(BT)(H₂O)₂]_n as a New Energetic Coordination Compound

Wang

Chen

Zhang

et al. 2018

Zeitschrift anorg allge chemie

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In order to enhance the thermal stability of the barium salt of 5,5Ј-bistetrazole (H 2 BT), carbohydrazide (CHZ) was used to build [Ba(CHZ)(BT)(H 2 O) 2 ] n as a new energetic coordination compound by using a simple aqueous solution method. It was characterized by FT-IR spectroscopy, elemental analysis, and single-crystal X-ray diffraction. The crystal belongs to the monoclinic P2 1 /c space group [a = 8.6827(18) Å, b = 17.945(4) Å, c = 7.2525 Å, β = 94.395(2)°, V = 1126.7(4) Å 3 , and ρ = 2.356 g·cm -3 ]. The Ba II cation is ten-coordinated with one BT 2-, two shared carbohydrazides, and four shared water molecules. The thermal stabilities were investigated by differential scanning calorimetry (DSC) and thermal gravity analysis (TGA). The dehyration temperature (T dehydro ) is at 187°C, whereas the decomposition temperature

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Effects of gold catalyst on the thermal decomposition characteristics and thermal safety of methylhydrazine

Yao

Li³

et al. 2022

J Therm Anal Calorim

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Synthesis, structure and characterization of 1-D polymer {[Sr(CHZ)₂(ClO₄)]ClO₄}_n: a new concept for designing primary explosives

Abstract: A new idea for designing energetic compounds: by introducing polymer structures to the molecule.

Cited by 3 publications

References 31 publications

Explosives in the Cage: Metal–Organic Frameworks for High‐Energy Materials Sensing and Desensitization

Explosives in the Cage: Metal–Organic Frameworks for High‐Energy Materials Sensing and Desensitization

Synthesis and Properties of [Ba(CHZ)(BT)(H₂O)₂]_n as a New Energetic Coordination Compound

Effects of gold catalyst on the thermal decomposition characteristics and thermal safety of methylhydrazine

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Synthesis, structure and characterization of 1-D polymer {[Sr(CHZ)2(ClO4)]ClO4}n: a new concept for designing primary explosives

Abstract: A new idea for designing energetic compounds: by introducing polymer structures to the molecule.

Cited by 3 publications

References 31 publications

Explosives in the Cage: Metal–Organic Frameworks for High‐Energy Materials Sensing and Desensitization

Explosives in the Cage: Metal–Organic Frameworks for High‐Energy Materials Sensing and Desensitization

Synthesis and Properties of [Ba(CHZ)(BT)(H2O)2]n as a New Energetic Coordination Compound

Effects of gold catalyst on the thermal decomposition characteristics and thermal safety of methylhydrazine

Contact Info

Product

Resources

About

Synthesis, structure and characterization of 1-D polymer {[Sr(CHZ)₂(ClO₄)]ClO₄}_n: a new concept for designing primary explosives

Synthesis and Properties of [Ba(CHZ)(BT)(H₂O)₂]_n as a New Energetic Coordination Compound