Synthesis, structure, and characterization of hybrid materials: [Ce(H2O)]2[O2C(CH2)2CO2]3 and [Sm(H2O)]2[O2C(CH2)2CO2]3·H2O

Reversible Breaking and Forming of Metal–Ligand Coordination Bonds: Temperature‐Triggered Single‐Crystal to Single‐Crystal Transformation in a Metal–Organic Framework

“…Rare-earth succinates have been studied widely and several inorganic-organic frameworks have been obtained and characterized. [3,[7][8][9][10][11][12][13][14] Although the properties of the rare-earth element and the flexible succinate anion are combined in these frameworks, the properties of the compounds such as luminescence [8,14,15] or catalysis [3] have been evaluated in only a few studies. However, the transformations of one hybrid polymeric structure to another are rare in solid-state supramolecular reactions as the breaking and formation of bonds should occur in more than one direction simultaneously.…”

The Effect of Hydrothermal and Non‐Hydrothermal Synthesis on the Formation of Holmium(III) Succinate Hydrate Frameworks

“…Lanthanide [21] Eu, [22] Gd [23] and Er; [24] [14] Pr, [25] Sm, [21,25] Gd [23] and Tb; [22] [26] (type 3). All of these have been obtained by hydrothermal synthesis or under high-temperature conditions and are 3D hybrid frameworks with channels that can host hydrogen-bonded hydration water molecules.…”

Poly[bis[aquaneodymium(III)]-μ2-oxalato-di-μ4-succinato]

“…2). Both lengths and angles within the succinate anions exhibit normal values (Seguatni et al, 2004). The oxalate ions are located on a center of inversion and act as double bidentate (tetradentate) ligands in a linear chain that connects two Nd atoms in two different layers to form a threedimensional framework (Fig.…”