Synthesis, structure and dielectric properties of a Cd coordination polymer based on homopiperazine

Shi, Qiu-Zhong; Xing, Zheng; Cao, Yong-Nan; Ma, Shi-Bing; Chen, Lizhuang

doi:10.1016/j.molstruc.2016.10.051

Cited by 9 publications

(6 citation statements)

References 28 publications

Supporting

Mentioning

Contrasting

Order By: Relevance

“…The values of C-C and C-N distances vary in the range of 1.510 (3)-1.520 (3) Å and in the range of 1.494 (3)-1.514 (3) Å while the values of the angles C-N-C and N-C-C range from 115.12 (17) to 117.94 ( 16) and from 111.65 (18) to 114.34 (18) • respectively, and the C-C-C angle is equal to 115.40 (18) • (Table S2). These values of bond distances and angles are comparable to those given in other hybrids containing hexahydro-1,4-diazepinediium as organic matrix [37,38].…”

Section: Resultssupporting

confidence: 85%

See 1 more Smart Citation

Organic–Inorganic Manganese (II) Halide Hybrid Combining the Two Isomers Cis/Trans of [MnCl4(H2O)2]: Crystal Structure, Physical Properties, Pharmacokinetics and Biological Evaluation

et al. 2023

View full text Add to dashboard Cite

A manganese (II) complex templated by hexahydro-1,4-diazepinediium as a counter ion was grown by slow evaporation from an aqueous solution at room temperature. The X-ray diffraction analysis revealed that the compound (C5H14N2)[MnCl4(H2O)2] crystallizes in the centrosymmetric space group P2/c of the monoclinic system. The crystal structure of the Mn(II) complex is characterized by an alternation of 0-dimensional organic and inorganic stacks linked together by N/O-H…Cl and N-H…O hydrogen bonds, which lead to a three-dimensional supramolecular architecture. In this structure, the inorganic layer is built up by independent anionic moieties combining the two isomers cis/trans of [MnCl4(H2O)2]2−. The thermal decomposition was studied by TGA-DTA techniques. The optical band gap and Urbach energy were obtained by Tauc’s equation. The direct and indirect band gap values are found to be 4.58 and 4.44 eV, respectively. Weak antiferromagnetic interactions are present in the molecule under study, according to magnetic measurements. An agar well diffusion technique was used to assess the synthetic compound’s biological activity, and the results showed that it has potent antibacterial (Gram-positive and Gram-negative) properties. Interestingly, the synthesized compound also displayed antilipase activity. These biological activities have been confirmed by the bioavailability and pharmacokinetic analyses.

show abstract

Section: Resultssupporting

confidence: 85%

“…S2). These values of bond distances and angles are comparable to those given in other hybrids containing hexahydro-1,4-diazepinediium as organic matrix [37,38].…”

Section: Resultssupporting

confidence: 85%

Organic–Inorganic Manganese (II) Halide Hybrid Combining the Two Isomers Cis/Trans of [MnCl4(H2O)2]: Crystal Structure, Physical Properties, Pharmacokinetics and Biological Evaluation

et al. 2023

View full text Add to dashboard Cite

show abstract

“…The C–C and N–C distances range from 1.448(19) to 1.512(16) Å and from 1.473(10) to 1.490 (12) Å, respectively (Table S1). These values are close to those given for hexahydrodiazepine derivatives. − The intermolecular hydrogen bonding contacts N–H···Br provide a linkage between the (C 5 H 14 N 2 ) 2+ cations and the [CuBr 4 ] 2– anions and give rise to a three-dimensional packing. The hydrogen bond parameters are depicted in Table S3.…”

Section: Resultsmentioning

confidence: 96%

Crystal Chemistry, Optic and Magnetic Characterizations of a New Copper Based Material Templated by Hexahydrodiazepine

et al. 2023

View full text Add to dashboard Cite

Crystals of the new organic−inorganic material (DAP-H2)[CuBr 4 ] (1); (DAP = hexahydrodiazepine (C 5 H 14 N 2 )) were successfully synthesized by slow evaporation and characterized by single-crystal X-ray diffraction, infrared spectroscopy, thermal analysis, UV−Vis−NIR diffuse reflectance spectroscopy, and magnetic measurements. X-ray investigation demonstrates that 1 crystallizes in the monoclinic space group C2/c. The supramolecular crystal structure of 1 is guided by several types of hydrogen bonding which connect anions and cations together into a three-dimensional network. The optical band gap was determined by diffuse reflectance spectroscopy to be 1.78 eV for a direct allowed transition, implying that it is suitable for light harvesting in solar cells. The vibrational properties of this compound were studied by infrared spectroscopy, while its thermal stability was established by simultaneous TGA−DTA from ambient temperature to 600 °C. The study of the photoresponse behavior of an optoelectronic device, based on (C 5 H 14 N 2 )[CuBr 4 ], has shown a power conversion efficiency (PCE) of 0.0017%, with J sc = 0.0208 mA/cm 2 , V oc = 313.7 mV, and FF = 25.46. Temperature dependent magnetic susceptibility measurements in the temperature range 1.8−310 K reveal weak antiferromagnetic interactions via the two-halide superexchange pathway [2J/k B = −8.4(3) K].

show abstract

“…The conductivity of both ligands log  (S/cm) and metal complexes increased proportionally with frequency and temperature [43]. Generally, conductivity is the free moving property of electrons.…”

Section: Dielectrical Propertiesmentioning

confidence: 99%

Preparation and Characterization of Styrene Bearing Diethanolamine Side Group, Styrene Copolymer Systems, and Their Metal Complexes

Açıkses

Çömez

Biryan

2018

International Journal of Polymer Science

View full text Add to dashboard Cite

The two copolymer systems of styrene bearing diethanol amine side group and styrene were prepared by free radical polymerization method at 60 ∘ C in presence of 1,4-dioxane as solvent and AIBN as initiator. Their metal complexes were prepared by reaction of the copolymer used as ligand P(DEAMSt-co-St)L and Ni(II) and Co(II) metal ions, which was carried out in presence of ethanol and NaOH at 65 ∘ C for 48 h in pH = 7.5. The structures of the copolymers used as ligand and metal complexes were identified by FT-IR, 1 H-NMR spectra, and elemental analysis. The properties of the copolymers used as ligand and metal complexes were characterized by SEM-EDX, AAS, DSC, TGA, and DTA techniques. Then, the electrical properties of the copolymers and metal complexes were examined as a function of the temperature and frequency, and the activation energies ( ) were estimated with conductivity measurements.

show abstract

Synthesis, structure and dielectric properties of a Cd coordination polymer based on homopiperazine

Cited by 9 publications

References 28 publications

Organic–Inorganic Manganese (II) Halide Hybrid Combining the Two Isomers Cis/Trans of [MnCl4(H2O)2]: Crystal Structure, Physical Properties, Pharmacokinetics and Biological Evaluation

Organic–Inorganic Manganese (II) Halide Hybrid Combining the Two Isomers Cis/Trans of [MnCl4(H2O)2]: Crystal Structure, Physical Properties, Pharmacokinetics and Biological Evaluation

Crystal Chemistry, Optic and Magnetic Characterizations of a New Copper Based Material Templated by Hexahydrodiazepine

Preparation and Characterization of Styrene Bearing Diethanolamine Side Group, Styrene Copolymer Systems, and Their Metal Complexes

Contact Info

Product

Resources

About