Synthesis, structure and electrochemical properties of diiron S-(−)-1-Phenylethylazadithiolate complexes

Li, Yulong; He, Jiao; Wei, Juan; Ji, Wei; Mu, Chao; Wu, Yu; Xie, Bin; Zou, Like; Wang, Zheng; Wu, Mei-Li; Li, Hanmin; Zhao, Pei‐Hua

doi:10.1016/j.poly.2017.08.023

Cited by 9 publications

(1 citation statement)

References 37 publications

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“…The new complex 2 is an air‐stable red solid, soluble in polar solvents, and was characterized using elemental analysis and spectroscopy. For instance, the IR spectrum shows three absorption bands in the region 1996–2077 cm −1 , which can be ascribed to the stretching vibrations of the terminal carbonyls, consistent with those of the all‐carbonyl diiron complexes . The 1 NMR spectrum displays a doublet at 4.22 ppm for the protons of the methylene group attached to the ester group.…”

Section: Resultsmentioning

confidence: 54%

Electrocatalytic properties of diiron ethanedithiolate complexes containing benzoate ester

Chen

et al. 2018

Applied Organom Chemis

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Six diiron ethanedithiolate complexes containing benzoate ester have been synthesized and characterized. Treatment of the starting material [{μ-SCH 2 CH(CH 2 OH)S}Fe 2 (CO) 6 ] (1) with benzoic acid in the presence of N,N′dicyclohexylcarbodiimide and 4-dimethylaminopyridine afforded the benzoate ester-containing complex [{μ-SCH 2 CH(CH 2 O 2 CPh)S}Fe 2 (CO) 6 ] (2) in 97% yield. Carbonyl substitution of complex 2 with a monophosphine ligand, such as triphenylphosphine, tris(2-methoxyphenyl)phosphine, tris(4-fluorophenyl) phosphine, isopropyldiphenylphosphine or cyclohexyldiphenylphosphine, in the presence of Me 3 NO⋅2H 2 O gave the derivatives [{μ-SCH 2 CH(CH 2 O 2 CPh)S} Fe 2 (CO) 5 L] (L = PPh 3 , 3; P(C 6 H 4 OCH 3 -2) 3 , 4; P(C 6 H 4 F-4) 3 , 5; Ph 2 PCH(CH 3 ) 2 , 6; Ph 2 PC 6 H 11 , 7) in 66-95% yields. Complexes 2-7 were characterized using elemental analysis, spectroscopy and X-ray diffraction analysis. In addition, these complexes can catalyze the reduction of protons to H 2 in the presence of weak acid HOAc under electrochemical conditions.

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Section: Resultsmentioning

confidence: 54%

Electrocatalytic properties of diiron ethanedithiolate complexes containing benzoate ester

Chen

et al. 2018

Applied Organom Chemis

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Synthesis and characterization of diiron ethane-1,2-dithiolate complexes with tricyclohexylphosphine, methyl diphenylphosphinite, or tris(2-thienyl)phosphine coligands

Yang

Xiao

et al. 2019

Transit Met Chem

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Synthesis, structures, and electrochemistry of diiron toluene-3,4-dithiolate complexes containing phosphine ligands

Lin

et al. 2019

Transit Met Chem

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Synthesis, structure and electrochemical properties of diiron S-(−)-1-Phenylethylazadithiolate complexes

Cited by 9 publications

References 37 publications

Electrocatalytic properties of diiron ethanedithiolate complexes containing benzoate ester

Electrocatalytic properties of diiron ethanedithiolate complexes containing benzoate ester

Synthesis and characterization of diiron ethane-1,2-dithiolate complexes with tricyclohexylphosphine, methyl diphenylphosphinite, or tris(2-thienyl)phosphine coligands

Synthesis, structures, and electrochemistry of diiron toluene-3,4-dithiolate complexes containing phosphine ligands

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