Synthesis, structure and magnetic properties of binuclear 3d-metal complexes of new 3-(2-pyridyl)-6-phenyl-1,2,4-triazine derivative

Nemytov, Alexey I.; Utepova, Irina A.; Кискин, М. А.; Efimov, Nikolay N.; Fedin, Matvey V.; Еременко, И. Л.; Musikhina, Alexandra A.; Слепухин, П. А.; Чупахин, О. Н.

doi:10.1016/j.poly.2020.114901

Cited by 2 publications

(1 citation statement)

References 46 publications

Supporting

Mentioning

Contrasting

Order By: Relevance

“…Triazines are good electron-acceptor organic compounds that have been used as electron transport layers in OLEDs [25][26][27]. The modification of triazine rings by various substituents at different positions is promising for the development of new organic devices [42,43].…”

Section: Introductionmentioning

confidence: 99%

Spectroscopic and Physicochemical Studies on 1,2,4-Triazine Derivative

et al. 2022

View full text Add to dashboard Cite

A novel 5-(5-Bromo-2-hydroxybenzylidene)-6-oxo-3-phenyl-5,6-dihydro-1,2,4-triazine-2(1H)-carbothioamide (4) “compound 4” was synthesized. The chemical structure of compound 4 was confirmed with spectroscopic techniques. Thermal analysis (TGA/dTGA) studies were conducted for identifying the kinetic thermodynamic parameters and the thermal stability of the synthesized compound 4. Cyclic voltammetric studies were performed for recognizing electrochemical characteristics of the synthesized compound 4. The calculated highest occupied molecular orbital (HOMO), lowest unoccupied molecular orbital (LUMO), and the band gap were found to be −3.61, −5.32, and 1.97 eV, respectively. Using a diffused reflectance spectroscopy (DRS) technique, the estimated values of the optical band transitions of compound 4 in powder form were found to be 2.07 and 2.67 eV. The structural properties of thermally evaporated compound 4 thin films were analyzed using field emission scanning electron microscopy (FESEM), X-ray diffraction (XRD), and Fourier transform infrared (FTIR) spectroscopy. It was found that compound 4 has a triclinic crystal structure. The optical transitions and the optical dispersion factors of compound 4 thin films were investigated using a UV-Vis spectroscopy technique. From the UV-Vis spectroscopy technique, Egind=3.6 V was estimated for both the as-deposited and annealed thin films. For the as-deposited film, there were two photoluminescence (PL) emission peaks centered at 473 and 490 nm with a shoulder at 422 nm. For the annealed film at 423 K, there were five PL emission peaks centered at 274, 416, 439, 464, and 707 nm with a shoulder at 548 nm. The dark electrical conduction of compound 4 thin film was through a thermally activated process with activation energy equaling 0.88 eV.

show abstract

Section: Introductionmentioning

confidence: 99%

Spectroscopic and Physicochemical Studies on 1,2,4-Triazine Derivative

et al. 2022

View full text Add to dashboard Cite

show abstract

Synthesis, Crystal Structure, Hirschfeld Surface Analysis and Catalytic Activity of a New Binuclear Zn(II) Complex Based on Homophthalic Acid and 2,2'-Bipyridine Ligands

Wang

Tai

2022

Bull. Chem. React. Eng. Catal.

View full text Add to dashboard Cite

A new binuclear Zn(II) complex, [Zn2L2(BIPY)2(H2O)2](1) (H2L = homophthalic acid, BIPY = 2,2'-bipyridine) has been synthesized by one-pot method of homophthalic acid, 2,2'-bipyridine, zinc acetate dihydrate, and NaOH in water/ethanol (v:v = 1:1) solution. The structure of complex (1) was characterized by IR and X-ray single-crystal diffraction analysis. The results show that each Zn(II) ion is five-coordinated with two carboxylic O atoms from two homophthalate ligands (O2, O3 or O2a, O3a), two N atoms from two 2,2'-bipyridine ligands (N1, N2 or N1a, N2a) and one O atom from coordinated water molecule (O5 or O5a), and forms a distorted trigonal bipyramid coordination geometry. Complex (1) forms 1D chained structure and 3D network structure by the p-p interaction of 2,2'-bipyridine ligands. The Hirschfeld surface analysis of complex (1) was calculated. The catalytic performance of complex (1) has also been investigated for the oxidation of benzyl alcohol under O2 atmosphere. The optimal reaction temperature and pressure were 100 °C and 0.3 MPa for complex (1). Copyright © 2022 by Authors, Published by BCREC Group. This is an open access article under the CC BY-SA License (https://creativecommons.org/licenses/by-sa/4.0).

show abstract

Synthesis, structure and magnetic properties of binuclear 3d-metal complexes of new 3-(2-pyridyl)-6-phenyl-1,2,4-triazine derivative

Cited by 2 publications

References 46 publications

Spectroscopic and Physicochemical Studies on 1,2,4-Triazine Derivative

Spectroscopic and Physicochemical Studies on 1,2,4-Triazine Derivative

Synthesis, Crystal Structure, Hirschfeld Surface Analysis and Catalytic Activity of a New Binuclear Zn(II) Complex Based on Homophthalic Acid and 2,2'-Bipyridine Ligands

Contact Info

Product

Resources

About