Synthesis, structure and photoluminescence of a 3D pillared heterometallic coordination polymer containing 2D inorganic cadmium‐potassium‐oxide layer subunits

Liu, Qing‐Yan; Wang, Yu‐Ling; Liu, Jiu‐Hui

doi:10.1002/crat.200800547

Cited by 4 publications

(1 citation statement)

References 32 publications

(25 reference statements)

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“…The K–O distances vary from 2.672(6) to 3.079(6) Å. The bond dimensions involving potassium are normal and are comparable to those in related potassium(I) complexes 28. The Cd1 atom is seven‐coordinate by four carboxylate oxygen atoms (O5, O2F, and O4H) from three SBTC 4– ligands, one sulfonate oxygen atom (O7H) from the fourth SBTC 4– ligand and two coordinated water molecules (O11 and O12).…”

Section: Resultsmentioning

confidence: 72%

Heteroacenes Bearing the Pyrimidine Scaffold: Synthesis, Photophysical and Electrochemical Properties

et al. 2016

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A convenient synthetic route to novel 7-substituted benzo[f ]thieno[3,2-h]quinazoline and 8-substituted benzo[g,h]-dithieno[2,3-e:3′,2′-j]perimidine systems, bearing the fused pyrimidine ring, has been advanced. A commercially available 5-bromopyrimidine was used as the starting material to obtain various polycyclic systems through the sequence of nucleophilic aromatic substitution of hydrogen (the S N H reaction),

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Section: Resultsmentioning

confidence: 72%

Heteroacenes Bearing the Pyrimidine Scaffold: Synthesis, Photophysical and Electrochemical Properties

et al. 2016

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Two Cadmium Coordination Compounds with 5‐Sulfonyl‐1,2,4‐benzenetricarboxylate Ligand: Syntheses, Structures, and Photoluminescence

Cao¹,

Liu²,

Li³

et al. 2014

Zeitschrift anorg allge chemie

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Two new cadmium(II) coordination compounds, [Cd4(SBTC)2(2,2′‐bpy)6(H2O)4](2,2′‐bpy) (1) (2,2′‐bpy = 2,2′‐bipyridyl) and {[K2Cd(SBTC)(H2O)4](H2O)2}n (2), were synthesized using a novel ligand of 5‐sulfonyl‐1,2,4‐bezenetricarboxylic acid (H4‐SBTC) featuring three carboxylate groups and one sulfonate group stationed on a phenyl central motif. Compound 1 is a discrete tetranuclear [Cd4(SBTC)2(2,2′‐bpy)6(H2O)4] structure with a solvated 2,2′‐bpy molecule, wherein the four cadmium ions are bridged by two μ3‐SBTC4– ligands. The discrete tetranuclear [Cd4(SBTC)2(2,2′‐bpy)6(H2O)4] motif is extended into a three‐dimensional (3D) supramolecular framework through hydrogen bonds and π–π interactions. In compound 2 the cadmium ions and potassium ions are interconnected by the SBTC4– ligands and bridging water molecules to give a complex 3D structure. The 3D structure is constructed by a rare 3D inorganic cadmium‐potassium‐oxide framework, in which the cadmium and potassium ions are bridged by the sulfonate groups and bridging water molecules. In the solid state, compounds 1 and 2 exhibit photoluminescence with emission maximum at 380 and 445 nm, respectively.

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Coordination modes, spectral, thermal and biological evaluation of hetero-metal copper containing 2-thiouracil complexes

Masoud

Soayed

El-Husseiny

2012

Spectrochimica Acta Part A: Molecular and Biomolecular Spectros

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Synthesis, structure and photoluminescence of a 3D pillared heterometallic coordination polymer containing 2D inorganic cadmium‐potassium‐oxide layer subunits

Cited by 4 publications

References 32 publications

Heteroacenes Bearing the Pyrimidine Scaffold: Synthesis, Photophysical and Electrochemical Properties

Heteroacenes Bearing the Pyrimidine Scaffold: Synthesis, Photophysical and Electrochemical Properties

Two Cadmium Coordination Compounds with 5‐Sulfonyl‐1,2,4‐benzenetricarboxylate Ligand: Syntheses, Structures, and Photoluminescence

Coordination modes, spectral, thermal and biological evaluation of hetero-metal copper containing 2-thiouracil complexes

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