Synthesis, structure, and photoluminescence properties of a novel 3D 3d-4f heterometallic polymer: Pr4(H2O)9Cu3.5Cl0.5(Bpdc)6.5(OH)2 · 5H2O (H2Bpdc = 2,2′-bipyridyl-5,5-dicarboxylic acid)

Cheng, Hongli; Shi, Dongying; Zhao, Junwei; Geng, Zhida; Chen, L. J.; Ma, P. T.; Niu, Jingyang

doi:10.1134/s1070328411030031

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A Series of Exceptionally Robust Luminescent Coordination Polymers Based on a Bipyridyldicarboxylate Ligand and Rare‐Earth‐Metal Ions

Tang

et al. 2013

Eur J Inorg Chem

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A series of three-dimensional rare-earth coordination polymers, [M 2 (bpdc) were synthesized by solvothermal reactions of 2,2Ј-bipyridine-5,5Ј-dicarboxylate (bpdc) with corresponding metal salts. Single-crystal and powder X-ray diffraction analyses demonstrated that these coordination polymers are isostructural. The carboxyl groups of the bpdc ligand are coordinated to metal ions and the 2,2Ј-bipyridine moieties are left free due to the preferable affinity of rare-earth metals for oxygen-donor atoms. The adjacent eight-coordinate MO 8 cores show dicapped trigonal prismatic environments; they are interconnected by carboxyl

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