Synthesis, structure, and properties of a new manganese thioantimonate(III),

Wang, Xin; Sheng, Tianlu; Hu, Shengmin; Fu, Ruibiao; Wu, Xin‐Tao

doi:10.1016/j.inoche.2009.02.028

Cited by 24 publications

(3 citation statements)

References 23 publications

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“…This problem can be overcome by using additional amines like ethylenediamine (en). Following this approach it was possible to prepare the compounds [Mn 4 (bipy) 2 Sb 4 S 10 ] (bipy = 2,2′-bipyridine), [Mn 2 (phen)Sb 2 S 5 ] (phen = 1,10-phenanthroline), and [TM(phen) 3 ] 2 Sb 18 S 29 (TM = Ni, Co). But this approach has the risk that the additional amine reacts with TM ions to form complexes or leads to crystallization of thioantimonates without the aromatic amines.…”

Section: Introductionmentioning

confidence: 99%

Fast Preparation of Dimorphic Thioantimonates and a Thioantimonate with a Hitherto Unknown Network Topology Applying a New Synthesis Approach

Anderer

Näther

Bensch

2016

Crystal Growth & Design

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The reaction of an aqueous solution of Na3SbS3 with [Ni(terpy)2]2+ (terpy = 2,2′:6′,2″-terpyridine) afforded crystallization of three new thioantimonates in short reaction times. Two polymorphic compounds, [Ni(terpy)2][Sb4S7]·H2O (1, 2), were obtained simultaneously under identical reaction conditions, while an increase of the reaction temperature led to formation of the third compound [Ni(terpy)2]2[Sb10S17] (3). In 1 the anion consists of a [Sb4S7]2– chain, whereas 2 is composed of a layered [Sb4S7]2– anion. Form 2 disappeared at longer reaction times, and therefore modification 1 might represent the thermodynamically stable form at this temperature despite the lower density compared to 2. Storing modification 1 at elevated temperatures the water can partly be removed in a topotactic reaction leading to the compound [Ni(terpy)2][Sb4S7]·0.25 H2O (1A). Compound 3 exhibits a unique Sb:S ratio, and a never before observed network topology significantly enhancing the structural diversity of thioantimonates(III).

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Section: Introductionmentioning

confidence: 99%

Fast Preparation of Dimorphic Thioantimonates and a Thioantimonate with a Hitherto Unknown Network Topology Applying a New Synthesis Approach

Anderer

Näther

Bensch

2016

Crystal Growth & Design

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“…Among the various organic molecules, organic structure-directing agents are more interesting because these molecules can act as different roles (e.g. template, charge-balance species, bridging ligands, solvents or their combination) during the crystal growth or in the final products [9][10][11][12][13][14][15][16][17][18]. However, finding a good organic structure-directing agent with multi-function to prepare new chalcogenides is challenging.…”

mentioning

confidence: 99%

A new hydrazine-bridged thioantimonate Mn2Sb4S8(N2H4)2: Synthesis, structure, optical and magnetic properties

Liu

Tian

Wei

et al. 2011

Inorganic Chemistry Communications

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“…On the basis of these synthetic methods, a large variety of thioantimonates with variable and fascinating structures were prepared. [6][7][8][9][10][11][12][13][14][15][16][17][18][19][20] During our systematic investigations of TM-Sb-S systems using different amines, transition metals (or transition metal complexes), and antimony sources, we were able to prepare a large number of compounds containing, for example, Cr, [21][22][23] Mn, [24][25][26][27][28][29][30][31][32] Fe, [33][34][35] Co, [36][37][38] Ni, [22,[39][40][41][42][43][44][45] Cu, [46,47] Zn, [48] or Ag [49] .…”

Section: Introductionmentioning

confidence: 99%

A Strategy for the Preparation of Thioantimonates Based on the Concept of Weak Acids and Corresponding Strong Bases

Anderer

Alarcón

Näther

et al. 2014

Chemistry A European J

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By following a new synthetic approach, which is based on the in situ formation of a basic medium by the reaction between the strong base Sb(V)S4 (3-) and the weak acid H2 O, it was possible to prepare three layered thioantimonate(III) compounds of composition [TM(2,2'-bipyridine)3 ][Sb6 S10 ] (TM=Ni, Fe) and [Ni(4,4'-dimethyl-2,2'-bipyridine)3 ][Sb6 S10 ] under hydrothermal conditions featuring two different thioantimonate(III) network topologies. The antimony source, Na3 SbS4 ⋅ 9 H2 O, undergoes several decomposition reactions and produces the Sb(III) S3 species, which condenses to generate the layered anion. The application of transition-metal complexes avoids crystallization of dense phases. The reactions are very fast compared to conventional hydrothermal/solvothermal syntheses and are much less sensitive to changes of the reaction parameters.

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Synthesis, structure, and properties of a new manganese thioantimonate(III),

Cited by 24 publications

References 23 publications

Fast Preparation of Dimorphic Thioantimonates and a Thioantimonate with a Hitherto Unknown Network Topology Applying a New Synthesis Approach

Fast Preparation of Dimorphic Thioantimonates and a Thioantimonate with a Hitherto Unknown Network Topology Applying a New Synthesis Approach

A new hydrazine-bridged thioantimonate Mn2Sb4S8(N2H4)2: Synthesis, structure, optical and magnetic properties

A Strategy for the Preparation of Thioantimonates Based on the Concept of Weak Acids and Corresponding Strong Bases

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