2015
DOI: 10.1016/j.poly.2015.07.053
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Synthesis, structure and solid luminescence of copper(I)–bromodiimine–diphosphine complexes

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Cited by 15 publications
(18 citation statements)
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“…The high energy absorptions (λ < 345 nm) are assigned to ligand-centred, spin-allowed transitions. The broad absorption bands with λ max in the range 415-420 nm (Table 3) ] is consistent with that reported for the corresponding perchlorate salt [26]. For both the POP-and xantphos-containing complexes, Figure 7 illustrates an increase in values of ε max on going from 2,9-Br 2 phen to 3,8-Br 2 phen to 4,7-Br 2 phen.…”
Section: Photophysical Propertiessupporting
confidence: 84%
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“…The high energy absorptions (λ < 345 nm) are assigned to ligand-centred, spin-allowed transitions. The broad absorption bands with λ max in the range 415-420 nm (Table 3) ] is consistent with that reported for the corresponding perchlorate salt [26]. For both the POP-and xantphos-containing complexes, Figure 7 illustrates an increase in values of ε max on going from 2,9-Br 2 phen to 3,8-Br 2 phen to 4,7-Br 2 phen.…”
Section: Photophysical Propertiessupporting
confidence: 84%
“…The broad absorption bands with λmax in the range 415-420 nm (Table 3) arise from metal-to-ligand charge transfer (MLCT). The profile of the absorption spectrum of [Cu(xantphos)(3,8-Br2phen)][PF6] is consistent with that reported for the corresponding perchlorate salt [26]. For both the POP-and xantphos-containing complexes, Figure 7 illustrates an increase in values of εmax on going from 2,9-Br2phen to 3,8-Br2phen to 4,7-Br2phen.…”
Section: Photophysical Propertiessupporting
confidence: 82%
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“…[1][2][3][4] Because the d 10 electron configuration of Cu(I) does not require a pre-defined spatial arrangement of the ligands (L), the coordination sphere is generally determined by molecular mechanics and electrostatic factors. 1,5 Among the CuX halides (X = F, Cl, Br or I) mostly used as precursors for the synthesis of these complexes, Cu(I) iodide (CuI) offers the advantages of higher chemical stability in oxidizing atmosphere and higher quantum efficiencies.…”
Section: Introductionmentioning
confidence: 99%