Synthesis, structure, and superconductivity of B-site doped perovskite bismuth lead oxide with indium

Abstract

Many elements can be doped into the A site of perovskite BaBiO3-based superconductors, but only Bi, Pb, Tl, Sb, Mg, and Na are found in the B site. Here, the...

Lanthanide-doped inorganic halide perovskites (CsPbX3): novel properties and emerging applications

“…Oxide perovskite A = inorganic cation B = inorganic cation X = oxygen SrTiO 3 , 40 GdScO 3 , 41 BaTiO 3 42 Organic-inorganic mixed halide perovskite (MA/FAPbCl 3ÀxÀy Br x I y ) A = organic cation B = inorganic cation X = two or more halide anions CH 3 NH 3 Pb(Br x I 1Àx ) 3 , 43 CH 3 NH 3 PbCl 0.5 Br 2. 5 44 Perovskite ABX 3 Hybrid perovskite A = organic cation (MA + , FA + ) B = inorganic cation X = halide anions Halide perovskite Organic-inorganic halide perovskite (MA/FAPbX 3 ) A = organic/inorganic cation (Cs + , MA + , FA + ) A = organic cation B = inorganic cation (Pb 2+ ) B = inorganic cation X = halide anions (Cl À , Br À , I À ) X = one halide anion HC(NH 2 ) 2 PbI 3 , 45 CH 3 NH 3 PbCl 3…”

“…58 It increased after the partial replacement of Cl À ions by Br À ions and attained the maximum value of about 80% for CsPbBr 3 . Further, the substitution of I-ions at Br-sites resulted in a decrease in PLQYs as CsPbI 3 shows PLQYs of about 58%. However, the synthesis method and the type of precursor used for the synthesis of the particular CsPbX 3 perovskite affected the PLQYs as well as the stability.…”

“…Oxide perovskites are well known for their versatile applications in many fields, for example, in piezoelectricity, magnetism, superconductivity, [1][2][3][4] etc. In the last two decades halide perovskites have shown a paradigm shift in the application of perovskites.…”

Spontaneous Reactivity of La2CuO4 toward CO2 Diagnosed Using Variable Temperature Raman Spectroscopy

“…Complex perovskite structures have a rich history due to their amenability to compositional tuning and defect engineering. − The ability to systematically tune the crystal structure of these materials provides the flexibility necessary to undertake extensive structure–property analyses to tailor the properties of these materials. − This capability has undoubtedly played a role in establishing perovskites as a leading material in applications ranging from superconductivity , to electrocatalysis. ,,− Advances in each of these fields requires well-controlled synthetic routes and considerations for the complexity of the medium in which the solids are utilized. Electrocatalytic reactions, for example, take place at an interface in a condensed phase medium.…”

High-yield synthesis of CsPbBr3 nanoparticles: diphenylphosphine as a reducing agent and its effect in Pb-seeding nucleation and growth

“…Perovskite-structured materials have gained importance in many state-of-the-art research fields such as nanocatalysis [1][2][3][4], superconductors [5][6][7][8] or piezoelectrics [9][10][11]; and just recently, the all-inorganic cesium-based lead halide perovskites (CsPbX 3 ; X=Cl, Br, I) have surged as colloidal materials for optoelectronics [12][13][14][15][16][17][18][19]. Due to their high photoluminescence quantum yields (PLQY) [16,19], tunable emission spectra [16,18], facile synthesis methods [17,20] and flexible ionic nature [16,20], these have been used as components in light emitting diodes (LED) [21,22], solar cells [23,24], lasers [25,26], and photodetectors [27,28]; hence, potentially competing with other semiconductor quantum dot (QD) systems [29][30][31].…”