Synthesis, structure and thermal stability of iodine-contained sodalites Na8(AlSiO4)6Cl2-I  (x = 0–2) for 129I immobilization

Two sodalite samples (sample I is Na8Al6Si6O24Cl2⋅0.4H2O from the Kovdor alkaline ultramafic massif with carbonatites in the Murmansk region, Russia, and sample II is Na8Al6Si6O24Cl2⋅0.2H2O from the Bayan Kol nepheline syenite and miaskite massif in the Republic of Tyva) were studied by thermal and electron-microprobe analyses, powder X-ray diffraction, photoluminescence, and by IR, Raman, and ESR spectroscopy. Solution melt calorimetry was applied to determine the enthalpy of formation from elements for water-bearing sodalite samples: −13536 ± 10 (I) and −13503 ± 19 (II) kJ/mol. The enthalpy of formation of sodalite of the theoretical composition Na8Al6Si6O24Cl2 was evaluated at ΔfH0(298.15 K) = −13446 ± 11 kJ/mol. The data obtained on the enthalpy of formation of sodalite and literature data on its S0(298.15 K) were used to calculate the standard Gibbs energies of formation of anhydrous and of water-bearing sodalite.

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Synthesis, structure and thermal stability of iodine-contained sodalites Na8(AlSiO4)6Cl2-I (x = 0–2) for 129I immobilization

Cited by 3 publications

References 36 publications

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Full-components utilization: Study on simultaneous preparation of sodalite and separation of yttrium from coal gangue by chlorination roasting process

Sodalite: Spectroscopic and Thermochemical Investigations

Sodalite: Spectroscopic and Thermochemical Investigations

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