Synthesis, Structures and DFT Studies of Imido‐bridged and (Bis)ligand‐coordinated Titanium Complexes

Abstract

Abstract. Syntheses and structures of five imido-bridged dinuclear titanium complexes and two (bis)ligand-coordinated mononuclear titanium complexes are reported. Addition of 1 or 2 equiv. of Schiff base ligand (((1H-pyrrol-2-yl)methylene)amino)-2,3-dihydro-1H-inden-2-ol (H 2 L) to Ti(NMe 2 ) 4 resulted in transamination with 4 equiv. of dimethylamides generating a (bis)ligand-coordinated complex Ti (L) 2 (1)