1991
DOI: 10.1021/om00051a016
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Synthetic and structural studies on organoiron-indium complexes

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Cited by 39 publications
(17 citation statements)
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“…Uncontracted Slater-type orbitals (STOs) using triple-z basis sets augmented by two sets of polarization functions were employed for the SCF calculations [43]. The (1s) 2 core electrons of carbon and nitrogen, (1s2s2p) 10 core electrons of copper, (1s2s2p3s3p) 18 core electrons of gallium, (1s2s2p3s3p3d) 28 core electrons of silver, and (1s2s2p3s3p3d4s4p4d) 46 core electrons of gold were treated by the frozen-core approximation [44]. An auxiliary set of s, p, d, f and g STOs was used to fit the molecular densities and to present the Coulomb and exchange potentials accurately in each SCF cycle [45].…”
Section: Methodsmentioning
confidence: 99%
“…Uncontracted Slater-type orbitals (STOs) using triple-z basis sets augmented by two sets of polarization functions were employed for the SCF calculations [43]. The (1s) 2 core electrons of carbon and nitrogen, (1s2s2p) 10 core electrons of copper, (1s2s2p3s3p) 18 core electrons of gallium, (1s2s2p3s3p3d) 28 core electrons of silver, and (1s2s2p3s3p3d4s4p4d) 46 core electrons of gold were treated by the frozen-core approximation [44]. An auxiliary set of s, p, d, f and g STOs was used to fit the molecular densities and to present the Coulomb and exchange potentials accurately in each SCF cycle [45].…”
Section: Methodsmentioning
confidence: 99%
“…Although a variety of systems including these lengths EX bridging between two metal centres have previously been characterised, complexes containing the heavier EX as terminal ligands have just previously been reported experimentally [85][86][87]. Dimeric complexes of the kind [(L n M) 2 E(μ-X) 2 E(ML n ) 2 ] or polymeric structure with sterically less hindered transition metal fragments [84,[121][122][123][124][125] are examples. The Lewis base coordinated at the group 13 centre can be used to segregate mononuclear systems in such circumstances [121,[126][127][128].…”
Section: Coordination Chemistry Of Heavier Group 13 Metal(i) Halidesmentioning
confidence: 99%
“…1. Volatile transition-metal-substituted alanes, gallanes, and indanes [5] The vapor pressure of the CoIn system 5, which is 0.020 (5) organic ligands or ligand fragments [9]). Table 1.…”
Section: -12mentioning
confidence: 99%
“…Table 1. Results of the analytical characterization of the thin films deposited from the precursors 1-6 according to Scheme 1 [8,9]. used.…”
Section: -12mentioning
confidence: 99%