Synthetic methods Part (ii) oxidation and reduction methods

Howard, J. K.; Hyland, Christopher J. T.

doi:10.1039/c2oc90014a

Annu. Rep. Prog. Chem., Sect. B: Org. Chem.

2012

DOI: 10.1039/c2oc90014a

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Synthetic methods Part (ii) oxidation and reduction methods

J. K. Howard

Christopher J. T. Hyland

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Cited by 4 publications

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References 134 publications

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“…Styrenes are versatile and important synthetic intermediates due to the wide array of methods available for the rapid functionalization of the vinyl group such as cross-metathesis, Mizoroki–Heck cross-coupling, and asymmetric dihydroxylation, aminohydroxylation, and epoxidation . In addition, styrenes are important inputs for the preparation of fine chemicals and polymers …”

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confidence: 99%

An Efficient Method for the Preparation of Styrene Derivatives via Rh(III)-Catalyzed Direct C–H Vinylation

Otley

Ellman

2015

Org. Lett.

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The development of a method for the Rh(III)-catalyzed direct vinylation of an aromatic C—H bond to give functionalized styrenes in good yield, using vinyl acetate as a convenient and inexpensive vinyl source is reported. High functional group tolerance is demonstrated for electronically distinct arenes as well as different directing groups. Mechanistic investigation resulted in the characterization of a novel rhodium-metallacycle, which represents the first x-ray structure of a [1,2]-Rh(III)-alkenyl addition adduct.

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confidence: 99%

An Efficient Method for the Preparation of Styrene Derivatives via Rh(III)-Catalyzed Direct C–H Vinylation

Otley

Ellman

2015

Org. Lett.

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Palladium on activated carbon catalyzed reductive amination of aldehydes and ketones by triethylsilane

Mirza‐Aghayan

Tavana

Rahimifard

et al. 2013

Applied Organom Chemis

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Various aldehydes and ketones were efficiently transformed into the corresponding amines using amine derivatives in the presence of triethylsilane and a catalytic amount of palladium on activated carbon in ethanol. The proposed method provides a one-pot synthesis of various amines in excellent yields after short reaction times. Scheme 2. Reductive amination of carbonyl compounds with primary and secondary amine derivatives. M. Mirza-Aghayan et al. wileyonlinelibrary.com/journal/aoc

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ChemInform Abstract: Synthetic Methods. Part 2. Oxidation and Reduction Methods

Howard

Hyland

2013

ChemInform

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Synthetic methods Part (ii) oxidation and reduction methods

Cited by 4 publications

References 134 publications

An Efficient Method for the Preparation of Styrene Derivatives via Rh(III)-Catalyzed Direct C–H Vinylation

An Efficient Method for the Preparation of Styrene Derivatives via Rh(III)-Catalyzed Direct C–H Vinylation

Palladium on activated carbon catalyzed reductive amination of aldehydes and ketones by triethylsilane

ChemInform Abstract: Synthetic Methods. Part 2. Oxidation and Reduction Methods

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