“…10 A monolayer ͑1 ML͒ of the same spheres was deposited on a glass substrate by using the LangmuirBlodgett ͑LB͒ technique. [11][12][13] As previously shown, 1 ML of spheres crystallize in a hexagonal lattice. 13 The LB approach was used because it has a distinct advantage over selfassembly for the preparation of samples with exact number of monolayers.…”
Diffraction in the face centered cubic lattice cannot explain some minima observed in the transmission spectra of self-assembled opal films. Here, we compared them with minima observed in the transmission spectra of a hexagonal close packed monolayer of spheres of the same diameter. The identity of the sphere packing on the surface of the opal film and in the sphere monolayer was demonstrated by the light diffraction at the sample surfaces. It was shown that excitation of surface propagating modes in the opal film is responsible for the formation of additional minima in opal film transmission. (C) 2008 American Institute of Physics. (DOI: 10.1063/1.2920443
“…10 A monolayer ͑1 ML͒ of the same spheres was deposited on a glass substrate by using the LangmuirBlodgett ͑LB͒ technique. [11][12][13] As previously shown, 1 ML of spheres crystallize in a hexagonal lattice. 13 The LB approach was used because it has a distinct advantage over selfassembly for the preparation of samples with exact number of monolayers.…”
Diffraction in the face centered cubic lattice cannot explain some minima observed in the transmission spectra of self-assembled opal films. Here, we compared them with minima observed in the transmission spectra of a hexagonal close packed monolayer of spheres of the same diameter. The identity of the sphere packing on the surface of the opal film and in the sphere monolayer was demonstrated by the light diffraction at the sample surfaces. It was shown that excitation of surface propagating modes in the opal film is responsible for the formation of additional minima in opal film transmission. (C) 2008 American Institute of Physics. (DOI: 10.1063/1.2920443
“…The methods of particle treatment and LB film deposition have been described previously, 11 with the key parameters being a substrate withdrawal speed of 0.5 cm min −1 , surface pressures between 3 and 6 mN m −1 , and a barrier speed equivalent to 6 cm 2 min −1 .…”
The Langmuir-Blodgett method was used to engineer photonic crystal thin films of an AB architecture. Structures were studied by transmittance and reflectance spectroscopies. For an AB structure in which the silica particle diameter B is twice that of A, reflectance features associated with the first order Bragg peak for the "A" domain are only observed when the structure is probed from the A side of the structure. Furthermore, this feature is enhanced in intensity compared to that for a structure consisting solely of A particles. These findings are attributed to a matching of first and second order Bragg processes. (c) 2006 American Institute of Physics. (DOI:10.1063/1.2339031
“…[6][7][8] The reported optical studies of LB multilayers dealt with wavelengths, which are larger than the sphere diameter by a factor of 2. Moreover, no spectroscopic evidence has been demonstrated to prove the formation of a 3D lattice in LB multilayers.…”
mentioning
confidence: 99%
“…12 A low barrier speed of 6 cm 2 / min and pressure of 4 mN/ m were used for the monolayer compression. LB monolayers of spheres crystallize in a hexagonal lattice.…”
mentioning
confidence: 99%
“…LB monolayers of spheres crystallize in a hexagonal lattice. 7 Subsequent layers were deposited after drying the deposited ones. Monolayer ͑1L͒ and up to ten-layer ͑10L͒ films were prepared.…”
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