Synthetic Strategies

doi:10.1002/9780470567548.ch12

Principles of Inorganic Materials Design 2010

DOI: 10.1002/9780470567548.ch12

|View full text |Cite

Synthetic Strategies

Help me understand this report

Search citation statements

Order By: Relevance

Paper Sections

Select...

Citation Types

Supporting

Mentioning

Contrasting

Year Published

2014

Publication Types

Select...

Article1

Relationship

Self Cite0

Independent1

Authors

Journals

Cited by 1 publication

References 35 publications

Supporting

Mentioning

Contrasting

Order By: Relevance

Syntheses, structures and properties of two dinuclear mercury(II) iodide compounds containing tetradentate tripodal amine/pentadentate N-donor Schiff base: Control of molecular and crystalline architectures by varying ligand matrices

et al. 2014

View full text Add to dashboard Cite

Two dinuclear mercury(II) iodide complexes of the types [(L1)Hg(µ-I)HgI 3 ] (1) and [Hg 2 (L2) (I) 4 ]•H 2 O (2) [L1 = tris(2-aminoethyl)amine and L2 = N,N-(bis-(pyridin-2-yl)benzylidene)diethylenetriamine] have been synthesized and characterized using microanalytical, spectroscopic, thermal and other physicochemical results. Structures of both the compounds are solved by X-ray diffraction measurements. Structural analyses show that one mercury (II) centre in 1 adopts a distorted tetrahedral geometry with an HgI 4 chromophore surrounded by four iodides, while the other has a distorted trigonal bipyramidal environment with an HgN 4 I chromophore bound by four N atoms of L1 and one bridging iodide. Pentadentate Schiff base (L2) in 2 shows unusual binucleating bis(bidentate) behaviour to bind two different mercury(II) centres-Hg1 with an HgN 3 I 2 chromophore in a distorted square pyramidal geometry and Hg2 with an HgN 2 I 2 chromophore in a tetrahedral environment. Weak intermolecular N-H•••I hydrogen bonds in 1 and cooperative C-H•••π and π •••π interactions in 2 promote dimensionalities. The Schiff base complex, 2, shows intraligand (π-π*) fluorescence in DMF solution at room temperature, whereas compound 1 containing tripodal amine is fluorescent-inactive.

show abstract

Syntheses, structures and properties of two dinuclear mercury(II) iodide compounds containing tetradentate tripodal amine/pentadentate N-donor Schiff base: Control of molecular and crystalline architectures by varying ligand matrices

et al. 2014

View full text Add to dashboard Cite

show abstract

scite is a Brooklyn-based organization that helps researchers better discover and understand research articles through Smart Citations–citations that display the context of the citation and describe whether the article provides supporting or contrasting evidence. scite is used by students and researchers from around the world and is funded in part by the National Science Foundation and the National Institute on Drug Abuse of the National Institutes of Health.

Contact Info

customersupport@researchsolutions.com

10624 S. Eastern Ave., Ste. A-614

Henderson, NV 89052, USA

This site is protected by reCAPTCHA and the Google Privacy Policy and Terms of Service apply.

Blog Terms and Conditions API Terms Privacy Policy Contact Cookie Preferences Do Not Sell or Share My Personal Information

Made with 💙 for researchers

Part of the Research Solutions Family.

Synthetic Strategies

Cited by 1 publication

References 35 publications

Syntheses, structures and properties of two dinuclear mercury(II) iodide compounds containing tetradentate tripodal amine/pentadentate N-donor Schiff base: Control of molecular and crystalline architectures by varying ligand matrices

Syntheses, structures and properties of two dinuclear mercury(II) iodide compounds containing tetradentate tripodal amine/pentadentate N-donor Schiff base: Control of molecular and crystalline architectures by varying ligand matrices

Contact Info

Product

Resources

About