Synthetically Induced 1→4‐C Branching Motif ‐ An Access Towards Dense Urethane Connecting Dendritic Scaffolds and Application in Nuclear Track Detection
Abstract:A series of dumbbell‐shaped urethane connecting polyoleifinic dendrimers, are synthesized from commercial AB2 monomer through the concept of post‐generative synthetic induction of novel 1→4‐C branching motif in divergent and convergent growth methodology using carbamoyl chloride reactivity. A synthetic protocol is conducted through the iterative process of O‐carbamoyl‐allylation of hydroxyls followed by Upjohn dihydroxylation of the allylic double bonds, leading to protection/deprotection free divergent pathwa… Show more
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