Systematic Literature Review of the Effect of Layered Double Hydroxides on the Mechanical Properties of Rubber

Abstract

Layered double hydroxides (LDHs) have attracted interest as reinforcing fillers in elastomers due to their ease of synthesis and customisability. A systematic review was performed on the effect of LDHs on the mechanical properties of elastomers using the Scopus database. Of the 61 articles relevant to the search criteria, the majority were published on polyurethane (PU) and nitrile butadiene rubber (NBR). Mg-Al LDH was used in most of the studies and Zn-Al LDH was used second most common. LDH can act as a reinforcing filler, typically increasing tensile strength even at low concentrations, so it could be used as an alternative to traditional reinforcing fillers for elastomers. LDH can also be made a functional filler by selecting the right metals and interlayer anions. It was found that Mg-Al LDH and Zn-Al LDH can both participate in crosslinking reactions and can replace MgO and ZnO, respectively. Less Zn ions are required for crosslinking when LDH is used than when ZnO is used, making LDH more environmentally friendly. Organic modification is usually required to improve compatibility with the elastomer matrix, especially in non-polar elastomers. It enables exfoliation of the LDH and intercalation of polymer chains into the LDH interlayer to occur. Organic modifiers can also be used to functionalise the LDH. Stearic acid used in crosslinking systems can be replaced by stearate anions from stearate-modified LDH.

Improved performance of layered double hydroxide/hydrogenated nitrile rubber composites by addition of sorbic acid

“…[21] As a typical two-dimensional nanomaterial with large aspect ratio, layered double hydroxide (LDH) is conducive to facilitate the stress transfer of rubber and effectively improve the mechanical properties of rubber. [22] The dense carbon layer formed by the degradation of LDH at high temperature could effectively block the transmission of gas and heat, therefore, LDH could effectively improve the thermal stability and flame retardancy of rubber. [23,24] The addition of LDH could also enhance the vulcanization performance and thermal-oxidative aging performance of rubber.…”