Systematic studies on Sr4La6(SiO4)6M2:Eu3+ (M = F/Cl) phosphors: effects of the halogen anions on photoluminescence

Shi, Lei; Zhao, Siwen; Zhao, Ying; Han, Ya-jie; Meng, Lei; Zhang, Meiyu; Zhang, Zhiwei

doi:10.1007/s10854-018-0452-8

Cited by 8 publications

(1 citation statement)

References 40 publications

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“…This energy is a measure of the thermal stability of the Eu 3+ emission; higher activation energies describe phosphors with high thermal stability of emission. The obtained value of gadolinium silicate apatite is superior to the values of 0.412 eV for Sr 4 La 6 (SiO 4 ) 6 F 2 :Eu 3+ , 22 The Judd-Ofelt (JO) theory allows for the quantitative analysis of f-f electronic transitions of lanthanide ions and provides the Judd-Ofelt intensity parameters (O 2 and O 4 ), the value of radiative lifetime and the intrinsic quantum yield. 51,52 The O 2 and O 4 parameters, as well as the relationship between both parameters, demonstrate the nature and extent of bonding of the Eu 3+ with the ligands and the degree of asymmetry around the metal ion site.…”

Section: Concentration Quenching Of Eu 3+ Emissionmentioning

confidence: 93%

Narrow-band red phosphors of high colour purity based on Eu³⁺-activated apatite-type Gd_9.33(SiO₄)₆O₂

et al. 2021

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Section: Concentration Quenching Of Eu 3+ Emissionmentioning

confidence: 93%

Narrow-band red phosphors of high colour purity based on Eu³⁺-activated apatite-type Gd_9.33(SiO₄)₆O₂

et al. 2021

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Site Substitution Toward Modified Spectral Behaviors in Ce³⁺‐Activated Sr₄La₆(SiO₄)₆Cl₂ Cyan‐Emitting Phosphors for Plant Growth and Full‐Spectrum White Light‐Emitting Diode

Guo,

Wang,

et al. 2024

Laser & Photonics Reviews

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Series of Ce3+‐activated Sr4La6(SiO4)6Cl2 (SLSOC) cyan‐emitting phosphors are designed to satisfy the demands of plant growth and full‐spectrum white‐light diode (white‐LED). Herein, to modify the luminescence behaviors of phosphors, Ce3+ is designed to occupy the different sites in SLSOC host lattices. Excited at 353 nm, the resultant phosphors emit glaring cyan emission originating from Ce3+ with an asymmetric emission band, which is assigned to the two‐site occupation of Ce3+ at Sr2+ or La3+ crystallographic sites. Moreover, the quantum efficiency and thermal quenching performances of synthesized phosphors are also analyzed, which are all dependent on the crystallographic sites taken by Ce3+. Via using the designed phosphors, two cyan‐emitting LEDs are packaged and their emissions are highly overlapped with the absorption spectra of plant pigments, which allow their feasibilities in plant growth. Furthermore, the artificial plant growth experiments are performed to clarify the significant positive influence of the packaged cyan‐emitting LEDs on plant growth. Additionally, via using the prepared cyan‐emitting phosphors to compensate the cyan gap, the full‐spectrum white‐LEDs with high electroluminescence performances are designed. These achievements reveal that the Ce3+‐activated SLSOC phosphors with controllable luminescence properties are promising cyan‐emitting converters for artificial plant growth LED and full‐spectrum white‐LED.

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Excellent photoluminescence and cathodoluminescence properties in Eu3+-activated Sr2LaNbO6 materials for multifunctional applications

Hua

Ran

2021

Chemical Engineering Journal

144

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Systematic studies on Sr4La6(SiO4)6M2:Eu3+ (M = F/Cl) phosphors: effects of the halogen anions on photoluminescence

Cited by 8 publications

References 40 publications

Narrow-band red phosphors of high colour purity based on Eu³⁺-activated apatite-type Gd_9.33(SiO₄)₆O₂

Narrow-band red phosphors of high colour purity based on Eu³⁺-activated apatite-type Gd_9.33(SiO₄)₆O₂

Site Substitution Toward Modified Spectral Behaviors in Ce³⁺‐Activated Sr₄La₆(SiO₄)₆Cl₂ Cyan‐Emitting Phosphors for Plant Growth and Full‐Spectrum White Light‐Emitting Diode

Excellent photoluminescence and cathodoluminescence properties in Eu3+-activated Sr2LaNbO6 materials for multifunctional applications

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Systematic studies on Sr4La6(SiO4)6M2:Eu3+ (M = F/Cl) phosphors: effects of the halogen anions on photoluminescence

Cited by 8 publications

References 40 publications

Narrow-band red phosphors of high colour purity based on Eu3+-activated apatite-type Gd9.33(SiO4)6O2

Narrow-band red phosphors of high colour purity based on Eu3+-activated apatite-type Gd9.33(SiO4)6O2

Site Substitution Toward Modified Spectral Behaviors in Ce3+‐Activated Sr4La6(SiO4)6Cl2 Cyan‐Emitting Phosphors for Plant Growth and Full‐Spectrum White Light‐Emitting Diode

Excellent photoluminescence and cathodoluminescence properties in Eu3+-activated Sr2LaNbO6 materials for multifunctional applications

Contact Info

Product

Resources

About

Narrow-band red phosphors of high colour purity based on Eu³⁺-activated apatite-type Gd_9.33(SiO₄)₆O₂

Narrow-band red phosphors of high colour purity based on Eu³⁺-activated apatite-type Gd_9.33(SiO₄)₆O₂

Site Substitution Toward Modified Spectral Behaviors in Ce³⁺‐Activated Sr₄La₆(SiO₄)₆Cl₂ Cyan‐Emitting Phosphors for Plant Growth and Full‐Spectrum White Light‐Emitting Diode