degree of the entire electronic systems. In the integrated flexible electronic system, energy storage devices [14,[16][17][18][19][20] play important roles in connecting the preceding energy harvesting devices and the following energy utilization devices (Figure 1). Rechargeable secondary batteries and supercapacitors (SCs) are two typical energy storage devices. [21] Several excellent review papers [21][22][23][24][25][26] reported significant progresses achieved in flexible lithium-ion batteries (LIBs) and SCs by taking advantage of novel electrode materials, current collectors, and solid-state electrolytes. The application areas and lifetime of flexible power sources strongly depend on their mechanical deformation tolerance and the electrical property retention under deformation. Qualified flexible power sources should be able to endure high strain induced by external mechanical deformation, such as bending, compressing, stretching, folding, and twisting, while maintaining their electrochemical performance stability and structural integrity. Therefore, the mechanical reliability assessment and electrical property analysis of flexible devices need to be given much attention for future application.Tolerance in bending into a certain curvature is the major mechanical deformation characteristic of flexible energy storage devices. Thus far, several bending characterization parameters and various mechanical methods have been proposed to evaluate the quality and failure modes of the said devices by investigating their bending deformation status and received strain. Some of these mechanical metrologies were derived from the early research on flexible semiconductor devices of micro-electromechanical system (MEMS) [27,28] and TFTs. [29] However, comparing those numerous measurement data with one another is difficult because of the various theories and methods adopted by different research groups and the lack of unified assessment criteria. [26] The flexibility of flexible devices is generally realized not only by use of intuitive soft electrode materials but also by optimizing their mechanical structural design. [25] Detailed analysis on bending mechanics combining experimental and theoretical results provide not only reliable test methods to describe the bending state but also guidance for configuration design of devices against mechanical failure.The current review emphasizes on three main points: (1) key parameters that characterize the bending level of flexible energy storage devices, such as bending radius, bending Flexible energy storage devices with excellent mechanical deformation performance are highly required to improve the integration degree of flexible electronics. Unlike those of traditional power sources, the mechanical reliability of flexible energy storage devices, including electrical performance retention and deformation endurance, has received much attention. To provide the guideline for the construction design of devices, the strain distribution and failure modes in the entire architecture should b...