Tailoring the structure of layered double oxide for enhancing adsorption of anionic chemicals on collagen fibers in chrome-free leather processing

Ma, Jianzhong; Chen, Hou; Shi, Jiabo; Yang, Xiaoyan

doi:10.1007/s10098-022-02366-2

Clean Techn Environ Policy

2022

DOI: 10.1007/s10098-022-02366-2

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Tailoring the structure of layered double oxide for enhancing adsorption of anionic chemicals on collagen fibers in chrome-free leather processing

Jianzhong Ma

Hou Chen

Jiabo Shi

et al.

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Cited by 3 publications

References 23 publications

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Controllable Strategy of Metal–Organic Framework Structural Stability: Regulation of Ligand Electronegativity by Esterification

Huang,

Ma,

Chen

et al. 2024

Advanced Science

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Structural stability of metal–organic framework (MOF) is crucial for their application, and thus it is of great significance to construct MOFs with controllable structural stability. Herein, a strategy based on adjusting the electronic environment of ligands to regulate the structure stability of MOF is proposed. Briefly, a novel Zr‐MOF (Zr‐TA) with hydroxyl groups is synthesized. The hydroxyl groups are esterified to obtain ester groups with stronger electronegativity, which can weaken the strength of coordination between metal ion and ligand, thereby regulating the structure stability of the Zr‐MOF. Notably, this strategy can achieve controllable adjustment of the structure by adding modifiers at the appropriate time. In this work, this strategy is used to greatly improving the binding ability of MOF and collagen fibers, the hydrothermal stability of crosslinked collagen fibers is enhanced by 82.6%. Surprisingly, this strategy can also be applied to other application fields that require dynamic changes in structural stability of MOF. It will open up a new pathway for controlling the structural stability and application performance of MOF.

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Controllable Strategy of Metal–Organic Framework Structural Stability: Regulation of Ligand Electronegativity by Esterification

Huang,

Ma,

Chen

et al. 2024

Advanced Science

View full text Add to dashboard Cite

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The CCLW collagen biocomposite consisting Ag–Fe3O4 nanoparticles as a novel biomaterial with a view to facile green approach

Mandal

Dhineshkumar²,

Sastry

2023

Clean Techn Environ Policy

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Facile synthesis of biochar/layered double oxides composite by one-step calcination for enhanced carbon dioxide (CO2) adsorption

et al. 2023

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Tailoring the structure of layered double oxide for enhancing adsorption of anionic chemicals on collagen fibers in chrome-free leather processing

Cited by 3 publications

References 23 publications

Controllable Strategy of Metal–Organic Framework Structural Stability: Regulation of Ligand Electronegativity by Esterification

Controllable Strategy of Metal–Organic Framework Structural Stability: Regulation of Ligand Electronegativity by Esterification

The CCLW collagen biocomposite consisting Ag–Fe3O4 nanoparticles as a novel biomaterial with a view to facile green approach

Facile synthesis of biochar/layered double oxides composite by one-step calcination for enhanced carbon dioxide (CO2) adsorption

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