Tamanrasset’s Clay Characterization and Use as Low Cost, Ecofriendly and Sustainable Material for Water Treatment: Progress and Challenge in Copper Cu (II)

Abstract

In this study, the adsorption of copper Cu (II) from aqueous solution, on Tamanrasset’s clay which is low cost adsorbent, was studied using batch experiments. The adsorption study includes both equilibrium adsorption isotherms and kinetics. The characterization of the adsorbent necessitated several methods such as X-Ray Diffraction, Scanning Electron Microscopy coupled with Energy Dispersive X-ray, BET for specific surface area determination, Fourier transform infrared spectroscopy and thermogravimetric analysis. Indeed, various parameters were investigated such as contact time, initial metal ion concentration, mass of solid, pH of the solution and temperature. The adsorption process as batch study was investigated under the previews experimental parameters. The results revealed that the adsorption capacity of Cu2+ is maximized at naturel pH of metal 5.5. Removal of copper by the clay of Tamanrasset (kaolinite) achieved equilibrium within 50 minutes; the results obtained were found to be fitted by the pseudo-second order kinetics model. The equilibrium process was well described by the Langmuir model and the maximum adsorption capacity was found to be 26.59 mg/g.

The Role of Surface Functional Groups of Iron Oxide, Organic Matter, and Clay Mineral Complexes in Sediments on the Adsorption of Copper Ions

“…Metal-hydrated oxides, organic matter, and clay minerals play indispensable roles in the adsorption processes of heavy metal pollution [5,6]. Additionally, the adsorption of heavy metals and clay minerals, co-precipitation of hydrated oxides of iron and manganese, a combination of organic molecular complexes or silicates, and other primary minerals in the crystal lattice have become important factors in the mitigation and removal of heavy metals, such as Cu, in water environment [7].…”