Tannery wastes-derived gelatin and carbon nanotubes composite beads: adsorption and reuse studies using tartrazine yellow dye

Abstract

Tartrazine yellow is a dye commonly used in the food, textile, cosmetic and pharmaceutical industries. The effluents generated containing this contaminant must be treated since it presents potential carcinogenicity to the cells. The adsorption stands out among the other techniques used to remove dye from wastewater due to its ease of operation and implementation, and high removal rate. However, the production of effective and low-cost adsorbents is a constant challenge. Gelatin is a promising compound for the production of adsorbent composites, enabling the improvement of its low mechanical properties and accelerated degradation, by the addition of carbonaceous, such as carbon nanotubes (CNT's). Taking into account economic and environmental aspects, gelatin can be recovered from chromium-tanned leather wastes (RCTLW). Thus, this work aimed to study the adsorption of the tartrazine yellow dye by adsorbent composites based on:(1) commercial gelatin/CNT's beads and (2) RCTLW gelatin/CNT's beads. Commercial and RCTLW gelatin composite beads showed an adsorption capacity of 202.39 and 131.32 mg.g -1 , respectively, estimated by the Langmuir model. In adsorption kinetics, the density continued to increase after 300 min for both the composite materials, with better prediction of the pseudo-first order model. In the reuse study, the commercial and RCTLW gelatin composite beads proved to be usable for up to 10 cycles, with regenerations of 45 to 68% and 45 to 61%, respectively. In general, the composite beads of gelatin showed promise for the adsorption of dyes, mainly RCTLW gelatin, since it makes possible the use and minimization of wastes.

Rapid adsorption of benzotriazole onto oxidized carbon cloth as an easily separable adsorbent

“…The adsorption capacity in the first cycle was 6.81 mg/g and increased in the range 7.61 mg/g to 8.84 mg/g from the second to the fifth cycle. Previous researchers 65 , 67 reported an increase in the adsorption capacity of other adsorbents relative to that of the first cycle.

Figure 5 Adsorption/regeneration cycles of Oxi-CC for BTR adsorption.

…”

“…The reusability is one of the critical features that determine the feasibility of practical application of an adsorbent 64 . A reusable adsorbent reduces both the cost of the adsorption process and the generated solid waste 65 . The primary requirement of a reusable adsorbent is regenerability.…”