tremendous attention in the biomedical and tribological field due to their green and environmentally friendly effect on the environment and the ecosystem. In particular, it is reported that the waterbased lubricants as a promising green and low-cost lubrication product has been developed and are expected to be applied in flame resistant hydraulic fluids and metalworking fluids. [1-3] However, it is that the water-based lubricants need to be improved because these lubricants still have disadvantages of poor lubrication, low viscosity and high corrosivity and these drawbacks are the major limitation for its application in tribological fields. Therefore, varieties of water-based additives have been developed such as rust-inhibitor, antiwear additives, preservative, and thickener, etc. [1-4] Although the existing water-based lubricant additive has improved their lubrication performance and anticorrosion performance, it is not widely promoted and applied in industrial production like oil-based lubricants because of their lower viscosity and volatile. To solve these problems, it is therefore imperative to develop a new high-efficiency water-based lubricant with excellent tribological properties. Supramolecular hydrogel can self-assembly form the network structure through H-bonding and hydrophobic interaction, and the water was trapped in this network structure. The supramolecular hydrogel with unique physical and chemical properties have attracted widespread attention for their ease of design, self-assembling nature, adjustable controllability, biocompatibility, biodegradability, and fast response, ect. [5-12] Recently, the supramolecular hydrogel has been displayed a wide range of promising applications including in medicine, chemistry, material, and biology. [13-29] Unfortunately, supramolecular hydrogel have rarely been tried as the lubricants in the lubrication field. Supramolecular oil gels have good tribological properties and have been developed rapidly as a new type lubricant. [30-33] So, can supramolecular hydrogel as a green lubricant be used in the field of lubrication like oil gels? Here, a novel supramolecular hydrogel lubricant with shear thinning and superior extreme-pressure and antiwear properties was prepared. The functionalized nitrogen and phosphorus small molecule (PM) that can self-assembly form fibrous The development of low-cost water-based products with environmentally friendly, flame-retardant, and excellent cooling performance is of immense scientific interest in lubrication. For this purpose, a series of water-based lubricant additives have been developed, but most of them lack practical application due to the problems of volatility and viscosity. Herein, a novel semisolid supramolecular hydrogel lubricating material of 2,4,6-triamino-1,3,5-triazin-1-ium diisopentyl phosphate is reported. The functionalized two-component gelator molecule can self-assemble through intermolecular interaction to form 3D network structure effectively traps the diethylene glycol or water-glycol, thereby improving...