The effect of heat treatment temperature on crystallization behavior of Na2O-Y2O3-SiO2 silicate glass system was studied by melting and crystallization method, and a kind of glass-ceramics containing Na3YSi2O7 crystal phase was obtained. The structure and morphology of the glass-ceramics were studied by X-Ray Diffraction (XRD), Scanning Electron Microscopy (SEM) and transmittance. The results show that the average size of 280nm microcrystals can be obtained by holding the precursor glass at 610 °C for 2 h. With the increase of heat treatment temperature from 610 °C to 640 °C, the permeability of glass-ceramics began to decline, and the glass gradually changed into glass-ceramics, and finally emulsified into ceramics. The results show that Na2O-Y2O3-SiO2 silicate glass system is sensitive to temperature, and its microstructure changes obviously in a short time. Therefore, the glass containing Na3YSi2O7 crystal phase is expected to become a new material with high performance, low price and wide application market because of its excellent performance, simple preparation technology and low manufacturing cost.