The hydrolysis of cellulose using carbonaceous solid acid (CSA) in an ionic liquid was studied. The types and concentrations of products generated during the hydrolysis of the cellulose under different conditions, including temperature, reaction time, water addition, and recycle time, were investigated. The CSA prepared in the study contained 1.45 mmol/g of acidic groups, which was higher than the theoretical amount of sulfonic groups. The highest yields of total reducing sugars (TRS) and glucose were obtained at 5% water content, 6 h of reaction time, and 140 °C. The cellulose was hydrolyzed effectively via catalysis of CSA in [AMIM][Cl] with a low water content. Analysis of the products under different conditions in this work provides a strong basis for the full use of hydrolyzed cellulose. Sciences, Guangzhou 510640, China; c: Collaborative Innovation Centre of Biomass Energy, Zhengzhou, 450002, China; *Corresponding author: qiwei@ms.giec.ac.cn
Keywords: Carbonaceous solid acid; Hydrolysis; Cellulose; Ionic liquid Contact information: a: State Key laboratory of Clean Energy Utilization, Zhejiang University, Hangzhou 310027, China; b: Guangzhou Institute of Energy Conversion, Key Laboratory of Renewable Energy, Chinese Academy of
INTRODUCTIONBiorefineries, which use raw materials including industrial and agricultural waste, urban garbage, and other environmental benign feedstocks instead of fossil fuels, have been receiving increased attention (Cardoen et al. 2015;Kamm et al. 2016;Papendiek et al. 2016). Biorefineries provide fuels and chemicals for use in transportation and various industries, solving some thorny environmental and energy problems at the same time (O'Callaghan 2016;Sadhukhan et al. 2016).Cellulose usually has the dominant content in the lignocellulosic biomass. It is a highly crystalline polymer (Bai et al. 2014) connected by β-glycosidic linkages (Rinaldi et al. 2008). Suganuma et al. (2008) applied a carbon material bearing SO3H groups to cellulose hydrolysis under hydrothermal conditions, which avoided recovery problems and high energy input of traditional mineral acid catalysts (Namchot et al. 2014). The yields of glucose and β-1,4 glucan were 4% and 64%, respectively, while the yields of the experimental group catalyzed by sulfuric acid were 10% and 38% under the same conditions, respectively. Thus, carbon-based solid acid (CSA) can replace mineral acid as the catalyst for the hydrolysis of cellulose; however, further research is needed to enhance the hydrolysis efficiency and yield of desired products.Glucans consist of more than 30 anhydroglucose units (AGU) and are insoluble in most common solvents (Percival Zhang et al. 2006) (Dutta et al. 2013;Liu et al. 2013;Lian et al. 2014). Interesting results were recorded in particular reactions catalyzed by CSA (Guo et al. 2012b;Bai et al. 2014). Furthermore, the types and contents of chemicals in the hydrolysate should be quantified. There have also been studies producing certain chemicals, especially 5-hydroxymethylfurfural (5-HMF) (Guo...