“…The UV–vis spectra of TFEO-Pcs are highly solvent- and concentration-dependent, which can be observed even by the naked eye. The protonation of Pcs has been well investigated because protonated Pcs are expected to find applications in various areas because of their electronic properties, which include absorption, fluorescence, aggregation, and photochemical features upon protonation. , Although the protonation of Pcs regularly requires acids, TFEO-Pcs are spontaneously protonated, even in neutral chlorinated solvents such as chloroform . Thus, TFEO-Pcs exhibit a very high susceptibility for the acceptance of protons via the nitrogen atom at the meso-position (Figure b), which is increased by the influence of the TFEO group at the α-position .…”