Telechelic block copolymer L-PPI-b-poly(epoxide-alt-PA) obtained via desulfonation of poly(o-nitrophenylsulfonyl-activated aziridines)

Liang, Zhuangzhuang; Ren, Feng; Hu, Chenyang; Gao, Zan; Pang, Xuan; Chen, Xuesi

doi:10.1039/d3py00620d

Polym. Chem.

2023

DOI: 10.1039/d3py00620d

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Telechelic block copolymer L-PPI-b-poly(epoxide-alt-PA) obtained via desulfonation of poly(o-nitrophenylsulfonyl-activated aziridines)

Zhuangzhuang Liang,

Feng Ren,

Chenyang Hu

et al.

Abstract: Copolymers combining polyesters derived from ROCOP of epoxides and anhydrides with linear polyamines will have broad structures and improved functionalities. Herein, by using o-nitrophenylsulfonyl (o-Ns) activated alaninol as bifunctional initiator,...

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2024

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Recent progress of heterocycle ring‐opening (co)polymerization for the synthesis of sequence‐controlled block polyesters and polycarbonates

Zhao,

Hu,

Pang

et al. 2024

Smart Molecules

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Aliphatic polyesters and polycarbonates are among the promising sustainable polymers, which exhibit unique degradability and chain‐chain interactions owing to their heterofunctionality. However, monocomponent aliphatic polyesters and polycarbonates usually suffer from inferior properties and functionalities. By contrast, precisely modulated block copolymers composed of polyesters and polycarbonates give rise to sustainable materials with tailored performance. An efficient approach to synthesize the block copolymers is the ring‐opening (co)polymerization of the heterocycle monomers. Herein, this review presents the heterocycle monomer ring‐opening (co)polymerization for the formation of sequence‐controlled block polyesters and polycarbonates. Available synthetic strategies, different monomers, monomer combinations and the catalyst systems for the formation of different block polyesters and polycarbonates are summarized.

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Recent progress of heterocycle ring‐opening (co)polymerization for the synthesis of sequence‐controlled block polyesters and polycarbonates

Zhao,

Hu,

Pang

et al. 2024

Smart Molecules

View full text Add to dashboard Cite

show abstract

scite is a Brooklyn-based organization that helps researchers better discover and understand research articles through Smart Citations–citations that display the context of the citation and describe whether the article provides supporting or contrasting evidence. scite is used by students and researchers from around the world and is funded in part by the National Science Foundation and the National Institute on Drug Abuse of the National Institutes of Health.

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Telechelic block copolymer L-PPI-b-poly(epoxide-alt-PA) obtained via desulfonation of poly(o-nitrophenylsulfonyl-activated aziridines)

Abstract: Copolymers combining polyesters derived from ROCOP of epoxides and anhydrides with linear polyamines will have broad structures and improved functionalities. Herein, by using o-nitrophenylsulfonyl (o-Ns) activated alaninol as bifunctional initiator,...

Cited by 1 publication

References 56 publications

Recent progress of heterocycle ring‐opening (co)polymerization for the synthesis of sequence‐controlled block polyesters and polycarbonates

Recent progress of heterocycle ring‐opening (co)polymerization for the synthesis of sequence‐controlled block polyesters and polycarbonates

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