Telechelics from methyl propene via cationic polymerisation

Nuyken, Oskar; Pask, Stephen D.; Vischer, Axel; Walter, Michael

doi:10.1002/masy.19860030111

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1988

2004

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Cited by 16 publications

References 18 publications

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Telechelic Polymers

Yaǧcı

Nuyken

Graubner

2004

Encyclopedia of Polymer Science and Technology

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In this article common synthetic routes toward telechelics, which are polymers with well‐defined functional end groups, are described. Telechelic polymers are available via radical, cationic, and anionic polymerization including reversible addition–fragmentation chain transfer polymerization, atom transfer radical polymerization, and nitroxide mediated polymerization. Furthermore, metathesis has become a valuable tool for the preparation of telechelics. Last but not least selected examples are presented in which step‐growth polymerization has been successfully applied for the synthesis of such well‐defined macromolecules. In specific cases chain scission can also be a useful route.

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Telechelic Polymers

Yaǧcı

Nuyken

Graubner

2004

Encyclopedia of Polymer Science and Technology

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Cationic polymerization of bis(1‐alkylvinyl)benzenes and related monomers, 1. Structure elucidation of 1,1,3‐trimethyl substituted polyindane

1989

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1,4-Bis(l-chloro-l-methylethyl)benzene (BINIFER)/borontrichloride is known to be a very efficient initiating system for cationic polymerization of e. g. isobutene at low temperature (< -60°C). However, at higher temperature this system polymerizes by its own. The obtained polymers show a remarkable, high thermal stability and are soluble in common solvents. The analytical results indicate a very uniform structure consisting exclusively of I , 1,3-trirnethyl indane-3,Sdiyl units. Other possible structures could be excluded. A mechanism explaining the surprisingly selective polyindane formation is discussed.

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The role of chain transfer processes in inifer/boron trichloride initiated polymerizations of isobutene

Mayr

Schade

1988

Makromol. Chem., Rapid Commun.

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Telechelics from methyl propene via cationic polymerisation

Cited by 16 publications

References 18 publications

Telechelic Polymers

Telechelic Polymers

Cationic polymerization of bis(1‐alkylvinyl)benzenes and related monomers, 1. Structure elucidation of 1,1,3‐trimethyl substituted polyindane

The role of chain transfer processes in inifer/boron trichloride initiated polymerizations of isobutene

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