Investigation of synthesized vinyl esters of several furancarboxylic acids: 2-furancarboxylic, 3-furancarboxylic, 5-formyl-2- furancarboxylic, 5-nitro-2-furanoic and 2,5-furandicarboxylic from vinyl acetate using the reaction vinyl substitution in the presence of the system: 2- chloro-4,6-dimethoxy-1,3,5-triazine, as well as Zn(OTf)2, 3,3’-Ph2BINOL- 2Li, KOtrBu and BuLi has been carried out. At the same time increasing of the catalytic activity of these systems was identified as following: 3,3’- Ph2BINOL-2Li < BuLi < KOtrBu < Zn(OTf)2. The influence of various factors on products yield was studied. Optimal conditions for the formation of vinyl esters of carboxylic acids were: temperature -30°C, the Zn(OTf)2 system, the molar ratio of carboxylic acid and vinyl acetate is 1:1.2. The yields of vinyl esters of the studied furancarboxylic acids has increased in the following order: vinyl ester of 5-nitro-2-furancarboxylic acid < vinyl ester of 5-formyl-2-furancarboxylic acid < vinyl ester of 2-furancarboxylic acid < vinyl ester of 3-furancarboxylic acid < vinyl ester 2 ,5- furandicarboxylic acid. The structure of the synthesized compounds was confirmed by IR, 1H, 13C spectroscopy and gas chromatography-mass spectrometry.