2019
DOI: 10.1039/c8tc06401f
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Temperature- and pressure-dependent studies of a highly flexible and compressible perovskite-like cadmium dicyanamide framework templated with protonated tetrapropylamine

Abstract: Perovskite-like [TPrA][Cd(dca)3] undergoes four temperature-induced phase transitions associated with dielectric anomalies and one pressure-induced phase transition into a monoclinic phase.

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Cited by 34 publications
(29 citation statements)
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“…The switchable property, i.e., a dielectric transition between low-and high-dielectric states, enriches the family of dielectric materials and would find applications in stimuli-responsive devices as switches, sensors, actuators and so on. [1][2][3][4][5][6] It is known that dipolar reorientation contributes greatly to switchable properties in molecular-based materials, compared with the other two intrinsic polarizability origins (electronic and ionic displacements). [7] Therefore, manipulation of the dynamics of the dipoles is the key to build moleculebased stimuli-responsive materials by motional changes of polar components between static and dynamic phases.…”
Section: Introductionmentioning
confidence: 99%
See 1 more Smart Citation
“…The switchable property, i.e., a dielectric transition between low-and high-dielectric states, enriches the family of dielectric materials and would find applications in stimuli-responsive devices as switches, sensors, actuators and so on. [1][2][3][4][5][6] It is known that dipolar reorientation contributes greatly to switchable properties in molecular-based materials, compared with the other two intrinsic polarizability origins (electronic and ionic displacements). [7] Therefore, manipulation of the dynamics of the dipoles is the key to build moleculebased stimuli-responsive materials by motional changes of polar components between static and dynamic phases.…”
Section: Introductionmentioning
confidence: 99%
“…Switchable properties are the main characteristic of stimuli‐responsive materials. The switchable property, i.e., a dielectric transition between low‐ and high‐dielectric states, enriches the family of dielectric materials and would find applications in stimuli‐responsive devices as switches, sensors, actuators and so on . It is known that dipolar reorientation contributes greatly to switchable properties in molecular‐based materials, compared with the other two intrinsic polarizability origins (electronic and ionic displacements) .…”
Section: Introductionmentioning
confidence: 99%
“…In molecular crystal, dipolar reorientation contributes greatly to tunable and switchable dielectric constant between high‐ and low‐dielectric state, compared with the electronic and ionic displacements . Therefore, manipulated dynamics of the dipoles is one of vital role to construct molecule‐based switchable dielectrics by motional changes of polar components between static and dynamic phases …”
Section: Introductionmentioning
confidence: 99%
“…Especially, halogenometallates including globular structures have made great progress . Intriguing property, such as dielectric transition, emerged with the structural changes via tilting and distortions of the anion tetrahedron, displacements of the metal ions, and/or disordering of the organic cations . However, the stimuli‐responsive dielectrics materials are still rarely explored.…”
Section: Introductionmentioning
confidence: 99%
See 1 more Smart Citation